ACTILOX® PA14 — Safety Data Sheet — Nabaltec AG

Page 1

Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA14

Nabaltec AG 92409 Schwandorf

Date printed 30.10.2018, Revision 30.10.2018 Version 02. Supersedes version: 01 Page 1 / 10

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

ACTILOX® PA14

1.2 Relevant identified uses of the substance or mixture and uses advised against

1.2.1 Relevant uses Additive, filler, process aid

1.2.2 Uses advised against None known.

1.3 Details of the supplier of the safety data sheet Company Nabaltec AG Postfach 1860 92409 Schwandorf / GERMANY Phone +49 (0) 9431-53-0 Fax +49 (0) 9431-53-289 Homepage www.nabaltec.de E-mail info@nabaltec.de

Address enquiries to Technical information info@nabaltec.de

Safety Data Sheet sdb@chemiebuero.de

1.4 Emergency telephone number Company +49 (0)9431 53222 (24h) +49 (0)9431 530 (24h)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture [REGULATION (EC) No 1272/2008] No classification.

2.2 Label elements

Hazard pictograms

Hazard statements none

Precautionary statements Although this product does not require a hazard warning label, we recommend that the safety advice should be observed. P284 In case of inadequate ventilation wear respiratory protection.

2.3 Other hazards

Human health dangers Frequent persistent contact with the skin can cause skin irritation. Prolonged and excessive contact can cause irritation of the respiratory tract.

Environmental hazards Does not contain any PBT or vPvB substances.

Other hazards Further hazards were not determined with the current level of knowledge.

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Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA14

Nabaltec AG 92409 Schwandorf

Date printed 30.10.2018, Revision 30.10.2018 Version 02. Supersedes version: 01 Page 2 / 10

SECTION 3: Composition / Information on ingredients

Product-type: The product is a mixture.

Range [%] Substance

> 30 Polydimethylsiloxane CAS: 63148-62-9, EINECS/ELINCS: Polymer > 30 Boehmite (Al(OH)O) CAS: 1318-23-6, EINECS/ELINCS: 215-284-3, Reg-No.: 01-2119555298-28-XXXX > 30 Silicium dioxide CAS: 112926-00-8/7631-86-9, EINECS/ELINCS: 231-545-4, Reg-No.: 01-2119379499-16-XXXX

Comment on component parts No dangerous components. Substances of Very High Concern - SVHC: substances are not contained or are below 0.1%.

SECTION 4: First aid measures

4.1 Description of first aid measures General information Take off contaminated clothing and wash before reuse.

Inhalation Ensure supply of fresh air. In the event of symptoms seek medical treatment.

Skin contact When in contact with the skin, clean with soap and water. Consult a doctor if skin irritation persists.

Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Ingestion Rinse out mouth and give plenty of water to drink. In the event of symptoms seek medical treatment.

4.2 Most important symptoms and effects, both acute and delayed None known.

4.3 Indication of any immediate medical attention and special treatment needed Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media Suitable extinguishing media Product itself is non-combustible. Fire extinguishing method of surrounding areas must be considered.

Extinguishing media that must not Full water jet. be used

5.2 Special hazards arising from the substance or mixture Risk of formation of toxic pyrolysis products.

5.3 Advice for firefighters Use self-contained breathing apparatus.

Fire residues and contaminated firefighting water must be disposed of in accordance within the local regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures Use breathing apparatus if exposed to dust. Avoid dust formation.

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Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA14

Nabaltec AG 92409 Schwandorf

Date printed 30.10.2018, Revision 30.10.2018 Version 02. Supersedes version: 01 Page 3 / 10

6.2 Environmental precautions Do not discharge into the drains/surface waters/groundwater.

6.3 Methods and material for containment and cleaning up Take up mechanically. Avoid production of dust. Dispose of absorbed material in accordance within the regulations.

6.4 Reference to other sections See SECTION 8+13

SECTION 7: Handling and storage

7.1 Precautions for safe handling Avoid the formation and deposition of dust. Provide vacuuming if dust raised.

After worktime and before work breaks the affected skin areas must be thoroughly cleaned. Use barrier skin cream. Do not eat, drink, smoke or take drugs at work.

7.2 Conditions for safe storage, including any incompatibilities Keep only in original container. Prevent penetration into the ground.

Do not store together with food and animal food/diet.

Store in a dry place.

7.3 Specific end use(s) See product use, SECTION 1.2

SECTION 8: Exposure controls / personal protection

8.1 Control parameters Ingredients with occupational exposure limits to be monitored (GB)

Substance

Silicium dioxide

CAS: 112926-00-8/7631-86-9, EINECS/ELINCS: 231-545-4, Reg-No.: 01-2119379499-16-XXXX

Long-term exposure: 4 mg/m³, total inhalable dust

DNEL

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

Industrial, inhalative, Long-term - local effects: 3,59 mg/m³.

general population, oral, Long-term - systemic effects: 2,37 mg/kg bw/day.

Silicium dioxide, CAS: 112926-00-8/7631-86-9

Industrial, inhalative, Long-term - systemic effects: 4 mg/m³.

PNEC

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

freshwater, 74,9 µg/L.

sewage treatment plants (STP), 20 mg/l.

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Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA14

Nabaltec AG 92409 Schwandorf

Date printed 30.10.2018, Revision 30.10.2018 Version 02. Supersedes version: 01 Page 4 / 10

8.2 Exposure controls

Additional advice on system design Ensure adequate ventilation on workstation. Pay attention to dust limit value (ACGHI-2011: 10 mg/m³ particle inhalable; 3 mg/m³ particle respirable). Measurement methods for taking workplace measurements must meet the performance requirements of DIN EN 482. For example, recommendations are given in the IFA's list of hazardous substances.

Eye protection Safety glasses. (EN 166:2001)

Hand protection 0,4mm Nitrile rubber, >480 min (EN 374-1/-2/-3). The details concerned are recommendations. Please contact the glove supplier for further information.

Skin protection Protective clothing.

Other Avoid contact with eyes and skin. Do not inhale dust.

Respiratory protection Respiratory protection mask in the event of high concentrations. Short term: filter apparatus, filter P2. (DIN EN 143)

Thermal hazards none

Delimitation and monitoring of the Protect the environment by applying appropriate control measures to prevent or limit environmental exposition emissions.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties Form powder

Color white

Odor odourless

Odour threshold not applicable

pH-value 8 - 9, (aqueous suspension)

pH-value [1%] not applicable

Boiling point [°C] not applicable

Flash point [°C] not applicable

Flammability (solid, gas) [°C] not applicable

Lower explosion limit not applicable

Upper explosion limit not applicable

Oxidising properties no

Vapour pressure/gas pressure [kPa] not applicable

Density [g/ml] 2,4 (20 °C / 68,0 °F)

Bulk density [kg/m³] not determined

Solubility in water <0,00009 g/l (20°C)

Partition coefficient [n-octanol/water] not applicable

Viscosity not applicable

Relative vapour density determined not applicable in air

Evaporation speed not applicable

Melting point [°C] not applicable

Autoignition temperature [°C] not self-igniting

Decomposition temperature [°C] > 200

9.2 Other information

none

SECTION 10: Stability and reactivity

10.1 Reactivity

No dangerous reactions known if used as directed.

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Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA14

Nabaltec AG 92409 Schwandorf

Date printed 30.10.2018, Revision 30.10.2018 Version 02. Supersedes version: 01 Page 5 / 10

10.2 Chemical stability

The product is stable under standard conditions.

10.3 Possibility of hazardous reactions

No hazardous reactions known.

10.4 Conditions to avoid

Strong heating, because the thermal decomposition starts from 200.

10.5 Incompatible materials

not applicable

10.6 Hazardous decomposition products

No hazardous decomposition products known.

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Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA14

Nabaltec AG 92409 Schwandorf

Date printed 30.10.2018, Revision 30.10.2018 Version 02. Supersedes version: 01 Page 6 / 10

SECTION 11: Toxicological information

11.1 Information on toxicological effects Acute toxicity

Product

ATE-mix, inhalative, > 20 mg/l 4h.

ATE-mix, dermal, > 2000 mg/kg.

ATE-mix, oral, > 2000 mg/kg.

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

LD50, oral, Rat: > 2000 mg/kg bw.

LC50, inhalative, Rat: 7,6 mg/l 4h.

NOAEL, oral, Rat: 30 mg/kg bw/day chronic (analogon).

NOAEC, inhalative, Rat: 70 mg/m³ subchronic (analogon).

Silicium dioxide, CAS: 112926-00-8/7631-86-9

LD50, dermal, Rabbit: > 5000 mg/kg (Lit.).

LD50, oral, Rat: > 10000 mg/kg (Lit.).

Serious eye damage/irritation Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Skin corrosion/irritation Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Respiratory or skin sensitisation Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Specific target organ toxicity — Does not contain a relevant substance that meets the classification criteria. single exposure Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Specific target organ toxicity — Does not contain a relevant substance that meets the classification criteria. repeated exposure Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Mutagenicity Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Reproduction toxicity Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Carcinogenicity Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Aspiration hazard Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled.

General remarks

none

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Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA14

Nabaltec AG 92409 Schwandorf

Date printed 30.10.2018, Revision 30.10.2018 Version 02. Supersedes version: 01 Page 7 / 10

SECTION 12: Ecological information

12.1 Toxicity Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

LC50, Salmo trutta: > 100 mg/l.

EC50, Daphnia magna: > 100 mg/l.

EC50, Selenastrum capricornutum: > 100 mg/l.

Silicium dioxide, CAS: 112926-00-8/7631-86-9

LC50, (96h), Brachidanio rerio: > 10000 mg/l (OECD 203).

EC50, (24h), Daphnia magna: > 10000 mg/l (OECD 202).

12.2 Persistence and degradability

Behaviour in environment not determined compartments

Behaviour in sewage plant not determined

Biological degradability not determined

12.3 Bioaccumulative potential

Accumulation in organisms is not expected.

12.4 Mobility in soil

not applicable

12.5 Results of PBT and vPvB assessment

Based on all available information not to be classified as PBT or vPvB respectively.

12.6 Other adverse effects

None known.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Waste material c It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison with the waste-disposal operator.

Product For recycling, consult manufacturer.

Waste no. (recommended) 061399

Contaminated packaging Uncontaminated packaging may be reused. Uncontaminated packaging may be taken for recycling.

Waste no. (recommended) 150101 150102

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Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA14

Nabaltec AG 92409 Schwandorf

Date printed 30.10.2018, Revision 30.10.2018 Version 02. Supersedes version: 01 Page 8 / 10

SECTION 14: Transport information

14.1 UN number Transport by land according to not applicable ADR/RID

Inland navigation (ADN) not applicable

Marine transport in accordance with not applicable IMDG

Air transport in accordance with IATA not applicable

14.2 UN proper shipping name Transport by land according to NO DANGEROUS GOODS ADR/RID

Inland navigation (ADN) NO DANGEROUS GOODS

Marine transport in accordance with NOT CLASSIFIED AS "DANGEROUS GOODS" IMDG

Air transport in accordance with IATA NOT CLASSIFIED AS "DANGEROUS GOODS"

14.3 Transport hazard class(es)

Transport by land according to not applicable ADR/RID

Inland navigation (ADN) not applicable

Marine transport in accordance with not applicable IMDG

Air transport in accordance with IATA not applicable

14.4 Packing group Transport by land according to not applicable ADR/RID

Inland navigation (ADN) not applicable

Marine transport in accordance with not applicable IMDG

Air transport in accordance with IATA not applicable

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Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA14

Nabaltec AG 92409 Schwandorf

Date printed 30.10.2018, Revision 30.10.2018 Version 02. Supersedes version: 01 Page 9 / 10

14.5 Environmental hazards Transport by land according to no ADR/RID

Inland navigation (ADN) no

Marine transport in accordance with no IMDG

Air transport in accordance with IATA no

14.6 Special precautions for user

Relevant information under SECTION 6 to 8.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code

not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EEC-REGULATIONS 1991/689 (2001/118); 2010/75; 2004/42; 648/2004; 1907/2006 (REACH); 1272/2008; 75/324/EEC (2016/2037/EC); (EU) 2015/830; (EU) 2016/131; (EU) 517/2014

TRANSPORT-REGULATIONS DOT-Classification, ADR (2017); IMDG-Code (2017, 38. Amdt.); IATA-DGR (2018).

NATIONAL REGULATIONS (GB): EH40/2005 Workplace exposure limits (Second edition, published December 2011).

- Observe employment restrictions no for people

- VOC (2010/75/CE) 0 %

15.2 Chemical safety assessment not applicable

SECTION 16: Other information

16.1 Hazard statements

(SECTION 03)

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Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA14

Nabaltec AG 92409 Schwandorf

Date printed 30.10.2018, Revision 30.10.2018 Version 02. Supersedes version: 01 Page 10 / 10

16.2 Abbreviations and acronyms: ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route RID = Règlement concernant le transport international ferroviaire de marchandises dangereuses ADN = Accord européen relatif au transport international des marchandises dangereuses par voie de navigation intérieure ATE = acute toxicity estimate CAS = Chemical Abstracts Service CLP = Classification, Labelling and Packaging DMEL = Derived Minimum Effect Level DNEL = Derived No Effect Level EC50 = Median effective concentration ECB = European Chemicals Bureau EEC = European Economic Community EINECS = European Inventory of Existing Commercial Chemical Substances ELINCS = European List of Notified Chemical Substances GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC-Code = International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk IC50 = Inhibition concentration, 50% IMDG = International Maritime Code for Dangerous Goods IUCLID = International Uniform ChemicaL Information Database LC50 = Lethal concentration, 50% LD50 = Median lethal dose LC0 = lethal concentration, 0% LOAEL = lowest-observed-adverse-effect level MARPOL = International Convention for the Prevention of Marine Pollution from Ships NOAEL = No Observed Adverse Effect Level NOEC = No Observed Effect Concentration PBT = Persistent, Bioaccumulative and Toxic substance PNEC = Predicted No-Effect Concentration REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals STP = Sewage Treatment Plant TLV®/TWA = Threshold limit value – time-weighted average TLV®STEL = Threshold limit value – short-time exposure limit VOC = Volatile Organic Compounds vPvB = very Persistent and very Bioaccumulative

16.3 Other information

Classification procedure

Modified position SECTION 2 been added: Further hazards were not determined with the current level of knowledge.

SECTION 4 been added: Take off contaminated clothing and wash before reuse.

SECTION 7 been added: Do not eat, drink, smoke or take drugs at work.

SECTION 7 been added: After worktime and before work breaks the affected skin areas must

be thoroughly cleaned.

SECTION 8 been added: Protect the environment by applying appropriate control measures

to prevent or limit emissions.

SECTION 8 been added: Measurement methods for taking workplace measurements must

meet the performance requirements of DIN EN 482. For example, recommendations are given in the IFA's list of hazardous substances.

Copyright: Chemiebüro®

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 170519 nbc00016 GB

ACTILOX® PA14 — Safety Data Sheet — Nabaltec AG

Full document text

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

SECTION 2: Hazards identification

2.3 Other hazards

SECTION 3: Composition / Information on ingredients

SECTION 4: First aid measures

SECTION 5: Fire-fighting measures

SECTION 6: Accidental release measures

SECTION 7: Handling and storage

SECTION 8: Exposure controls / personal protection

8.2 Exposure controls

SECTION 9: Physical and chemical properties

9.2 Other information

SECTION 10: Stability and reactivity

10.6 Hazardous decomposition products

SECTION 11: Toxicological information

SECTION 12: Ecological information

12.6 Other adverse effects

SECTION 13: Disposal considerations

SECTION 14: Transport information

14.3 Transport hazard class(es)

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code

SECTION 15: Regulatory information

SECTION 16: Other information

16.1 Hazard statements

16.3 Other information

SECTION 4 been added: Take off contaminated clothing and wash before reuse.

SECTION 7 been added: Do not eat, drink, smoke or take drugs at work.

SECTION 7 been added: After worktime and before work breaks the affected skin areas must

SECTION 8 been added: Protect the environment by applying appropriate control measures

SECTION 8 been added: Measurement methods for taking workplace measurements must