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APYRAL AOH & ACTILOX — Boehmite SDS

Supplier safety data sheet for the listed APYRAL AOH and ACTILOX boehmite product families. Includes substance identification, handling, exposure controls and transport information.

Publisher
Nabaltec AG
Document type
SDS
Material
Boehmite
CAS
1318-23-6
Product code
APYRAL AOH, APYRAL AOH BFG, ACTILOX AS / B / SM
Language
English
Revision
14.07.2022 · Version 15.0
Region
European Union · REACH
Pages
11
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Page 1

Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM

Nabaltec AG 92409 Schwandorf

Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 1 / 11

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Valid for all product variants

Registration number 01-2119555298-28-XXXX

IUPAC Boehmite (Al(OH)O)

EINECS/ELINCS 215-284-3

CAS 1318-23-6

1.2 Relevant identified uses of the substance or mixture and uses advised against

1.2.1 Relevant uses

Flame retardant, additive, filler, pigment, ground chemical, health care, personal care, viscosity adjustor

1.2.2 Uses advised against

None known.

1.3 Details of the supplier of the safety data sheet

Company Nabaltec AG Postfach 1860 92409 Schwandorf / GERMANY Phone +49 (0) 9431-53-0 Fax +49 (0) 9431-53-289 Homepage www.nabaltec.de E-mail info@nabaltec.de

Address enquiries to

Technical information info@nabaltec.de

Safety Data Sheet sdb@chemiebuero.de (No dispatch of safety data sheets)

Safety data sheets are available from the supplier.

1.4 Emergency telephone number

Company +49 (0)9431 53222 (24h) +49 (0)9431 530 (24h)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture [REGULATION (EC) No 1272/2008]

No classification.

2.2 Label elements

Hazard pictograms

Hazard statements none

2.3 Other hazards

Physico-chemical hazards not applicable

Human health dangers Contains no ingredients with endocrine-disrupting properties.

Environmental hazards Does not contain any PBT or vPvB substances.

Other hazards none

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU

Page 2

Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM

Nabaltec AG 92409 Schwandorf

Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 2 / 11

SECTION 3: Composition / Information on ingredients

3.1 Substances

The product is a substance.

Range [%] Substance

>99 Boehmite (Al(OH)O) CAS: 1318-23-6, EINECS/ELINCS: 215-284-3, Reg-No.: 01-2119555298-28-XXXX

Comment on component parts No dangerous components. Substances of Very High Concern - SVHC: substances are not contained or are below 0.1%.

3.2 Mixtures

not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures

General information Change powdered clothing.

Inhalation Ensure supply of fresh air. In the event of symptoms seek medical treatment.

Skin contact When in contact with the skin, clean with soap and water. Consult a doctor if skin irritation persists.

Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Ingestion Rinse out mouth and give plenty of water to drink. In the event of symptoms seek medical treatment.

4.2 Most important symptoms and effects, both acute and delayed

None known.

4.3 Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Product itself is non-combustible. Fire extinguishing method of surrounding areas must be considered.

Extinguishing media that must not Full water jet. be used

5.2 Special hazards arising from the substance or mixture

none

5.3 Advice for firefighters

Use self-contained breathing apparatus.

Fire residues and contaminated firefighting water must be disposed of in accordance within the local regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use breathing apparatus if exposed to dust. Avoid dust formation. Ensure adequate ventilation.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU

Page 3

Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM

Nabaltec AG 92409 Schwandorf

Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 3 / 11

6.2 Environmental precautions

Do not discharge into the drains/surface waters/groundwater.

6.3 Methods and material for containment and cleaning up

Take up mechanically. Avoid production of dust. Dispose of absorbed material in accordance within the regulations.

6.4 Reference to other sections

See SECTION 8+13

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Avoid the formation and deposition of dust. Provide vacuuming if dust raised. Use only in well-ventilated areas.

Wash hands before breaks and after work. Use barrier skin cream.

7.2 Conditions for safe storage, including any incompatibilities

Keep only in original container. Prevent penetration into the ground.

Do not store together with food and animal food/diet.

Store in a dry place.

7.3 Specific end use(s)

See product use, SECTION 1.2

SECTION 8: Exposure controls / personal protection

8.1 Control parameters

Ingredients with occupational exposure limits to be monitored (EU)

not relevant

DNEL

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

Industrial, inhalative, Long-term - local effects, 3.59 mg/m³

general population, oral, Long-term - systemic effects, 2.37 mg/kg bw/day

PNEC

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

freshwater, 74.9 µg/L

sewage treatment plants (STP), 20 mg/L

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU

Page 4

Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM

Nabaltec AG 92409 Schwandorf

Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 4 / 11

8.2 Exposure controls

Additional advice on system design Ensure adequate ventilation on workstation. Pay attention to dust limit value (ACGIH-2011: 10 mg/m³ particle inhalable; 1,25 mg/m³ particle respirable). Measurement methods for taking workplace measurements must meet the performance requirements of DIN EN 482. For example, recommendations are given in the IFA's list of hazardous substances.

Eye protection Safety glasses. (EN 166:2001)

Hand protection 0.11mm Nitrile rubber, >480 min (EN 374-1/-2/-3). The details concerned are recommendations. Please contact the glove supplier for further information.

Skin protection Protective clothing (EN 340)

Other Do not inhale dust. Avoid contact with eyes and skin. Personal protective equipment should be selected specifically for the working place, depending on concentration and quantity handled. The resistance of this equipment to chemicals should be ascertained with the respective supplier.

Respiratory protection In the event of occupational exposure limits being exceeded or of inadequate ventilation: wear appropriate respiratory protection. Short term: filter apparatus, filter P2. (DIN EN 143)

Thermal hazards none

Delimitation and monitoring of the Protect the environment by applying appropriate control measures to prevent or limit environmental exposition emissions.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU

Page 5

Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM

Nabaltec AG 92409 Schwandorf

Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 5 / 11

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state solid

Form powder

Color white

Odor odourless

Odour threshold not applicable

pH-value 9 - 10 (20°C / 68°F) (aqueous suspension)

pH-value [1%] not applicable

Boiling point [°C] not relevant

Flash point [°C] not applicable

Flammability not applicable

Lower explosion limit not applicable

Upper explosion limit not applicable

Oxidising properties no

Vapour pressure/gas pressure [kPa] not applicable

Density [g/cm³] 3.0 (20°C / 68°F)

Relative density not determined

Bulk density [kg/m³] not determined

Solubility in water <0.00009 g/l (20°C / 68°F)

Solubility other solvents not required

Partition coefficient [n-octanol/water] not applicable

Kinematic viscosity not applicable

Relative vapour density not applicable

Evaporation speed not applicable

Melting point [°C] not relevant

Auto-ignition temperature [°C] not self-igniting

Decomposition temperature [°C] > 340°C / 644°F

Particle characteristics not relevant

9.2 Other information

none

SECTION 10: Stability and reactivity

10.1 Reactivity

No dangerous reactions known if used as directed.

10.2 Chemical stability

The product is stable under standard conditions.

10.3 Possibility of hazardous reactions

No hazardous reactions known.

10.4 Conditions to avoid

Strong heating, because the thermal decomposition starts from 340°C / 644°F.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU

Page 6

Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM

Nabaltec AG 92409 Schwandorf

Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 6 / 11

10.5 Incompatible materials

Acids Alkalies

10.6 Hazardous decomposition products

No hazardous decomposition products known.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU

Page 7

Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM

Nabaltec AG 92409 Schwandorf

Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 7 / 11

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute oral toxicity

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

LD50, oral, Rat, > 2000 mg/kg bw

NOAEL, oral, Rat, 30 mg/kg bw/day chronic (analogon)

Acute dermal toxicity

Product

Based on the available information, the classification criteria are not fulfilled.

Acute inhalational toxicity

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

LC50, inhalative, Rat, 7.6 mg/l 4h

NOAEC, inhalative, Rat, 70 mg/m³ subchronic (analogon)

Serious eye damage/irritation Non-corrosive / non-irritating.

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

Eye, non-irritating

Skin corrosion/irritation Non-corrosive / non-irritating.

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

dermal, non-irritating

Respiratory or skin sensitisation Non-sensitizing.

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

inhalative, non-sensitizing

dermal, non-sensitizing

Specific target organ toxicity — No classification. single exposure

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

inhalative, non-irritating

Specific target organ toxicity — No classification. repeated exposure

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

inhalative, no adverse effect observed

oral, no adverse effect observed

Mutagenicity There is no evidence of any mutagenic effects.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU

Page 8

Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM

Nabaltec AG 92409 Schwandorf

Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 8 / 11

Reproduction toxicity There is no evidence of any reproductive toxicity effects.

Carcinogenicity There is no evidence of any carcinogenic effects.

Aspiration hazard No classification.

General remarks

none

11.2 Information on other hazards

Endocrine disrupting properties Contains no ingredients with endocrine-disrupting properties.

Other information none

SECTION 12: Ecological information

12.1 Toxicity

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

LC50, Salmo trutta, > 100 mg/l

EC50, Daphnia magna, > 100 mg/l

EC50, Selenastrum capricornutum, > 100 mg/l

12.2 Persistence and degradability

Behaviour in environment not determined compartments

Behaviour in sewage plant not determined

Biological degradability not applicable

12.3 Bioaccumulative potential

not applicable

12.4 Mobility in soil

not determined

12.5 Results of PBT and vPvB assessment

not applicable

12.6 Endocrine disrupting properties

Contains no ingredients with endocrine-disrupting properties.

12.7 Other adverse effects

None known.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU

Page 9

Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM

Nabaltec AG 92409 Schwandorf

Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 9 / 11

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison with the waste-disposal operator.

Product

For recycling, consult manufacturer.

Waste no. (recommended) 061399

Contaminated packaging

Uncontaminated packaging may be reused. Uncontaminated packaging may be taken for recycling.

Waste no. (recommended) 150101 150102

SECTION 14: Transport information

14.1 UN number or ID number

Transport by land according to not applicable ADR/RID

Inland navigation (ADN) not applicable

Marine transport in accordance with not applicable IMDG

Air transport in accordance with IATA not applicable

14.2 UN proper shipping name

Transport by land according to NO DANGEROUS GOODS ADR/RID

Inland navigation (ADN) NO DANGEROUS GOODS

Marine transport in accordance with NOT CLASSIFIED AS "DANGEROUS GOODS" IMDG

Air transport in accordance with IATA NOT CLASSIFIED AS "DANGEROUS GOODS"

14.3 Transport hazard class(es)

Transport by land according to not applicable ADR/RID

Inland navigation (ADN) not applicable

Marine transport in accordance with not applicable IMDG

Air transport in accordance with IATA not applicable

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU

Page 10

Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM

Nabaltec AG 92409 Schwandorf

Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 10 / 11

14.4 Packing group

Transport by land according to not applicable ADR/RID

Inland navigation (ADN) not applicable

Marine transport in accordance with not applicable IMDG

Air transport in accordance with IATA not applicable

14.5 Environmental hazards

Transport by land according to no ADR/RID

Inland navigation (ADN) no

Marine transport in accordance with no IMDG

Air transport in accordance with IATA no

14.6 Special precautions for user

Relevant information under SECTION 6 to 8.

14.7 Maritime transport in bulk according to IMO instruments

not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EEC-REGULATIONS 2008/98/EC 2000/532/EC); 2010/75/EU; 2004/42/EC; (EC) 648/2004; (EC) 1907/2006 (REACH); (EU) 1272/2008; 75/324/EEC ((EC) 2016/2037); (EU) 2020/878; (EU) 2016/131; (EU) 517/2014

TRANSPORT-REGULATIONS ADR (2023); IMDG-Code (2023, 41. Amdt.); IATA-DGR (2023)

NATIONAL REGULATIONS (EU):

- Observe employment restrictions no for people

- VOC (2010/75/CE) 0 %

15.2 Chemical safety assessment

For this substance a chemical safety assessment has been carried out.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU

Page 11

Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM

Nabaltec AG 92409 Schwandorf

Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 11 / 11

SECTION 16: Other information

16.1 Abbreviations and acronyms:

ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route RID = Règlement concernant le transport international ferroviaire de marchandises dangereuses ADN = Accord européen relatif au transport international des marchandises dangereuses par voie de navigation intérieure ATE = acute toxicity estimate CAS = Chemical Abstracts Service CLP = Classification, Labelling and Packaging DMEL = Derived Minimum Effect Level DNEL = Derived No Effect Level EC50 = Median effective concentration ECB = European Chemicals Bureau EEC = European Economic Community EINECS = European Inventory of Existing Commercial Chemical Substances EL50 = Median effective loading ELINCS = European List of Notified Chemical Substances EmS = Emergency Schedules GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC-Code = International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk IC50 = Inhibition concentration, 50% IMDG = International Maritime Code for Dangerous Goods IUCLID = International Uniform ChemicaL Information Database IVIS = In vitro irritation score LC50 = Lethal concentration, 50% LD50 = Median lethal dose LC0 = lethal concentration, 0% LOAEL = lowest-observed-adverse-effect level LL50 = Median lethal loading LQ = Limited Quantities MARPOL = International Convention for the Prevention of Marine Pollution from Ships NOAEL = No Observed Adverse Effect Level NOEC = No Observed Effect Concentration PBT = Persistent, Bioaccumulative and Toxic substance PNEC = Predicted No-Effect Concentration REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals STP = Sewage Treatment Plant TLV®/TWA = Threshold limit value – time-weighted average TLV®STEL = Threshold limit value – short-time exposure limit VOC = Volatile Organic Compounds vPvB = very Persistent and very Bioaccumulative

16.2 Other information

Classification procedure

Modified position none

Copyright: Chemiebüro®

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU