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Cerablak® HTP-100 Spray Can — Safety Data Sheet — Phone Number Phone: (847) 807-4077 ext. (202) or ext. (222)

of the chemical and restrictions on use

Publisher
Phone Number Phone: (847) 807-4077 ext. (202) or ext. (222)
Document type
SDS
Material
CAS No Weight-%
CAS
64-17-5; 74-98-6; 1344-28-1; 75-28-5; 1318-23-6; 409-21-2
Product code
Cerablak® HTP-100 Spray Can
Language
English
Revision
21-Jan-2022 · Version 1
Region
Not stated
Pages
9
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Page 1

Safety Data Sheet

Issue Date: 21-Jan-2022 Revision Date: 21-Jan-2022 Version 1

1. IDENTIFICATION

Product identifier Product Name Cerablak® HTP-100 Spray Can

Other means of identification SDS # AFTI-109

UN/ID No 1950

Recommended use of the chemical and restrictions on use Recommended Use For industrial use.

Details of the supplier of the safety data sheet Supplier Address Applied Thin Films, Inc. 8261 Elmwood Ave. Skokie, IL. 60077

Emergency telephone number Company Phone Number Phone: (847) 807-4077 ext. (202) or ext. (222) Fax: (847) 807-4088 Emergency Telephone INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America)

2. HAZARDS IDENTIFICATION

Physical state Liquid

Classification

Serious eye damage/eye irritation Category 2 Germ cell mutagenicity Category 1B Carcinogenicity Category 1A Aerosols Category 1 Gases under pressure Compressed gas

Signal Word Danger

Hazard statements Causes serious eye irritation May cause genetic defects May cause cancer Extremely flammable aerosol Contains gas under pressure; may explode if heated

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AFTI-109 - Cerablak® HTP-100 Spray Can Revision Date: 21-Jan-2022 _____________________________________________________________________________________________ Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Keep away from heat/sparks/open flames/hot surfaces. — No smoking Pressurized container: Do not pierce or burn, even after use Do not spray on an open flame or other ignition source

Precautionary Statements - Response If exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention

Precautionary Statements - Storage Store locked up Protect from sunlight. Store in a well-ventilated place Do not expose to temperatures exceeding 50 °C/122 °F

Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant

Other hazards Toxic to aquatic life with long lasting effects

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name CAS No Weight-% Ethyl Alcohol 64-17-5 Proprietary Propane 74-98-6 Proprietary Aluminum Oxide 1344-28-1 Proprietary Isobutane 75-28-5 Proprietary Boehmite 1318-23-6 Proprietary Aluminum Phosphate Polymer Proprietary Proprietary Silicon Carbide 409-21-2 Proprietary

**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**

4. FIRST AID MEASURES

Description of first aid measures

General Advice If exposed or concerned: Get medical advice/attention.

Eye Contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes.

Inhalation Remove to fresh air.

Ingestion Clean mouth with water and drink afterwards plenty of water.

Most important symptoms and effects, both acute and delayed

Symptoms Causes serious eye irritation. May cause genetic defects. May cause cancer.

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AFTI-109 - Cerablak® HTP-100 Spray Can Revision Date: 21-Jan-2022 _____________________________________________________________________________________________ Indication of any immediate medical attention and special treatment needed

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media Not determined.

Specific Hazards Arising from the Chemical Extremely flammable aerosol. Contains gas under pressure; may explode if heated.

Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions Use personal protective equipment as required.

Environmental precautions

Environmental precautions See Section 12 for additional Ecological Information.

Methods and material for containment and cleaning up

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Clean-Up Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on Safe Handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wash face, hands and any exposed skin thoroughly after handling. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source.

Conditions for safe storage, including any incompatibilities

Storage Conditions Store locked up. Protect from sunlight. Store in a well-ventilated place. Do not expose to temperatures exceeding 50 °C/122°F.

Incompatible Materials None known based on information supplied.

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AFTI-109 - Cerablak® HTP-100 Spray Can Revision Date: 21-Jan-2022 _____________________________________________________________________________________________

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Ethyl Alcohol STEL: 1000 ppm TWA: 1000 ppm IDLH: 3300 ppm 64-17-5 TWA: 1900 mg/m3 TWA: 1000 ppm (vacated) TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1900 mg/m3 Propane : See Appendix F: Minimal TWA: 1000 ppm IDLH: 2100 ppm 74-98-6 Oxygen Content, explosion TWA: 1800 mg/m3 TWA: 1000 ppm hazard (vacated) TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1800 mg/m3 Aluminum Oxide TWA: 1 mg/m3 respirable TWA: 15 mg/m3 total dust - 1344-28-1 particulate matter TWA: 5 mg/m3 respirable fraction (vacated) TWA: 10 mg/m3 total dust (vacated) TWA: 5 mg/m3 respirable fraction Isobutane STEL: 1000 ppm explosion - TWA: 800 ppm 75-28-5 hazard TWA: 1900 mg/m3 Aluminum Phosphate Polymer TWA: 1 mg/m3 respirable - - Proprietary particulate matter Boehmite TWA: 1 mg/m3 respirable - - 1318-23-6 particulate matter Silicon Carbide TWA: 10 mg/m3 nonfibrous, TWA: 15 mg/m3 total dust TWA: 10 mg/m3 total dust 409-21-2 inhalable particulate matter, TWA: 5 mg/m3 respirable fraction TWA: 5 mg/m3 respirable dust particulate matter containing no (vacated) TWA: 10 mg/m3 total asbestos and <1% crystalline dust silica (vacated) TWA: 5 mg/m3 TWA: 3 mg/m3 nonfibrous, respirable fraction respirable particulate matter, particulate matter containing no asbestos and <1% crystalline silica TWA: 0.1 fiber/cm3 respirable fibers, including whiskers, length >5 µm, aspect ratio >=3:1 as determined by the membrane filter method at 400-450X magnification (4-mm objective), using phase-contrast illumination.

Appropriate engineering controls

Engineering Controls Apply technical measures to comply with the occupational exposure limits.

Individual protection measures, such as personal protective equipment

Eye/Face Protection Refer to 29 CFR 1910.133 for eye and face protection regulations.

Skin and Body Protection Refer to 29 CFR 1910.138 for appropriate skin and body protection.

Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements.

General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state Liquid Appearance Not determined Odor Not determined Color Not determined Odor Threshold Not determined _____________________________________________________________________________________________

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AFTI-109 - Cerablak® HTP-100 Spray Can Revision Date: 21-Jan-2022 _____________________________________________________________________________________________ Property Values Remarks • Method pH Not determined Melting point / freezing point Not determined Boiling point / boiling range Not determined Flash point -98 °C / -145 °F Evaporation Rate Not determined Flammability (Solid, Gas) Liquid-Not applicable Flammability Limit in Air Upper flammability or explosive Not determined limits Lower flammability or explosive Not determined limits Vapor Pressure Not determined Vapor Density Not determined Relative Density Not determined Water Solubility Not determined Solubility in other solvents Not determined Partition Coefficient Not determined Autoignition temperature Not determined Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined

10. STABILITY AND REACTIVITY

Reactivity Not reactive under normal conditions.

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous reactions None under normal processing.

Conditions to Avoid Keep out of reach of children.

Incompatible materials None known based on information supplied.

Hazardous decomposition products None known based on information supplied.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Eye Contact Avoid contact with eyes.

Skin Contact Avoid contact with skin.

Inhalation Do not inhale.

Ingestion Do not ingest.

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AFTI-109 - Cerablak® HTP-100 Spray Can Revision Date: 21-Jan-2022 _____________________________________________________________________________________________ Component Information

Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Ethyl Alcohol = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h 64-17-5 Propane - - > 800000 ppm ( Rat ) 15 min 74-98-6 Aluminum Oxide > 5000 mg/kg ( Rat ) - - 1344-28-1 Isobutane - - = 658 mg/L ( Rat ) 4 h 75-28-5 Boehmite > 5050 mg/kg ( Rat ) - > 5.09 mg/L ( Rat ) 4 h 1318-23-6

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms Please see section 4 of this SDS for symptoms.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Serious eye damage/eye Causes serious eye irritation. irritation

Germ cell mutagenicity May cause genetic defects.

Carcinogenicity May cause cancer.

Numerical measures of toxicity

The following values are calculated based on chapter 3.1 of the GHS document Oral LD50 9,703.20 mg/kg ATEmix (inhalation-dust/mist) 271.10 mg/L

12. ECOLOGICAL INFORMATION

Ecotoxicity Toxic to aquatic life with long lasting effects.

Component Information

Chemical name Algae/aquatic plants Fish Crustacea Ethyl Alcohol 12.0 - 16.0: 96 h Oncorhynchus 9268 - 14221: 48 h Daphnia magna 64-17-5 mykiss mL/L LC50 static mg/L LC50 13400 - 15100: 96 h Pimephales 2: 48 h Daphnia magna mg/L EC50 promelas mg/L LC50 flow-through Static 100: 96 h Pimephales promelas mg/L LC50 static Chemical name Algae/aquatic plants Fish Crustacea Boehmite 100: 96 h Oncorhynchus mykiss 100: 48 h Daphnia magna mg/L 1318-23-6 mg/L LC50 semi-static EC50 100: 96 h Pimephales promelas mg/L LC50 semi-static

Persistence/Degradability Not determined.

Bioaccumulation There is no data for this product.

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AFTI-109 - Cerablak® HTP-100 Spray Can Revision Date: 21-Jan-2022 _____________________________________________________________________________________________ Mobility

Chemical name Partition coefficient Ethyl Alcohol -0.32 64-17-5 Propane 2.3 74-98-6 Isobutane 2.88 75-28-5

Other Adverse Effects Not determined

13. DISPOSAL CONSIDERATIONS

Waste Treatment Methods

Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations.

California Hazardous Waste Status

Chemical name California Hazardous Waste Status Ethyl Alcohol Toxic 64-17-5 Ignitable

14. TRANSPORT INFORMATION

Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.

DOT UN/ID No 1950 Proper Shipping Name Aerosols Hazard class 2.1

IATA UN number UN1950 Proper Shipping Name Aerosols, flammable Transport hazard class(es) 2.1

IMDG UN number UN1950 Proper Shipping Name Aerosols Transport hazard class(es) 2.1

15. REGULATORY INFORMATION

International Inventories

Chemical name TSCA TSCA Inventory DSL/NDSL EINECS/ELI ENCS IECSC KECL PICCS AICS Status NCS Ethyl Alcohol X ACTIVE X X X X X X X Propane X ACTIVE X X X X X X X Aluminum Oxide X ACTIVE X X X X X X X Isobutane X ACTIVE X X X X X X X

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AFTI-109 - Cerablak® HTP-100 Spray Can Revision Date: 21-Jan-2022 _____________________________________________________________________________________________ Chemical name TSCA TSCA Inventory DSL/NDSL EINECS/ELI ENCS IECSC KECL PICCS AICS Status NCS Aluminum Phosphate X ACTIVE X X X X X X X Polymer Boehmite X ACTIVE X X X X X Silicon Carbide X ACTIVE X X X X X X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

US Federal Regulations

CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355).

SARA 313

Chemical name CAS No Weight-% SARA 313 - Threshold Values % Aluminum Oxide - 1344-28-1 1344-28-1 Proprietary 1.0

CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

US State Regulations

California Proposition 65 This product contains the following Proposition 65 chemicals.

Chemical name California Proposition 65 Ethyl Alcohol - 64-17-5 Carcinogen Developmental

U.S. State Right-to-Know Regulations

Chemical name New Jersey Massachusetts Pennsylvania Ethyl Alcohol X X X 64-17-5 Propane X X X 74-98-6 Aluminum Oxide X X X 1344-28-1 Isobutane X X X 75-28-5 Aluminum Phosphate Polymer X Proprietary Silicon Carbide X X X 409-21-2

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AFTI-109 - Cerablak® HTP-100 Spray Can Revision Date: 21-Jan-2022 _____________________________________________________________________________________________

16. OTHER INFORMATION

NFPA Health Hazards Flammability Instability Special Hazards Not determined Not determined Not determined Not determined HMIS Health Hazards Flammability Physical hazards Personal Protection Not determined Not determined Not determined Not determined

Issue Date: 21-Jan-2022 Revision Date: 21-Jan-2022 Revision Note: New format

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

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