Modified surface — Safety Data Sheet — Nabaltec AG

Page 1

Safety Data Sheet (UK REACH) (GB) ACTILOX®, APYRAL® AOH

Nabaltec AG 92409 Schwandorf

Date printed 30.05.2022, Revision 30.05.2022 Version 02. Supersedes version: 01 Page 1 / 10

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Modified surface Valid for all product variants

ACTILOX® AS1, ACTILOX® ES1, ACTILOX® HS1, ACTILOX® VS1 ACTILOX® B AS1, ACTILOX® B ES1, ACTILOX® B HS1

ACTILOX® B VS1, APYRAL® AOH AS1, APYRAL® AOH ES1

APYRAL® AOH HS1, APYRAL® AOH VS1

1.2 Relevant identified uses of the substance or mixture and uses advised against

1.2.1 Relevant uses

Flame retardant, additive, filler, pigment, ground chemical, health care, personal care, viscosity adjustor

1.2.2 Uses advised against

None known.

1.3 Details of the supplier of the safety data sheet

Company Nabaltec AG Postfach 1860 92409 Schwandorf / GERMANY Phone +49 (0) 9431-53-0 Fax +49 (0) 9431-53-289 Homepage www.nabaltec.de E-mail info@nabaltec.de

Address enquiries to

Technical information info@nabaltec.de

Safety Data Sheet sdb@chemiebuero.de

1.4 Emergency telephone number

Company +49 (0)9431 53222 (24h) +49 (0)9431 530 (24h)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture [REGULATION (GB) CLP]

No classification.

2.2 Label elements

The product does not require a hazard warning label in accordance with regulation CLP.

Hazard pictograms none

Signal word none

Hazard statements none

Precautionary statements none

2.3 Other hazards

Human health dangers Prolonged and excessive contact can cause irritation of the respiratory tract. Contains no ingredients with endocrine-disrupting properties.

Environmental hazards Does not contain any PBT or vPvB substances.

Other hazards Further hazards were not determined with the current level of knowledge.

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Page 2

Safety Data Sheet (UK REACH) (GB) ACTILOX®, APYRAL® AOH

Nabaltec AG 92409 Schwandorf

Date printed 30.05.2022, Revision 30.05.2022 Version 02. Supersedes version: 01 Page 2 / 10

SECTION 3: Composition / Information on ingredients

3.1 Substances

not applicable

3.2 Mixtures

The product is a mixture.

Range [%] Substance

>= 95 Boehmite (Al(OH)O) CAS: 1318-23-6, EINECS/ELINCS: 215-284-3, Reg-No.: 01-2119555298-28-XXXX <= 5 Polymer compound (except from registration)

Comment on component parts No dangerous components. Substances of Very High Concern - SVHC: substances are not contained or are below 0.1%.

SECTION 4: First aid measures

4.1 Description of first aid measures

General information Change powdered clothing.

Inhalation Ensure supply of fresh air. In the event of symptoms seek medical treatment.

Skin contact When in contact with the skin, clean with soap and water. Consult a doctor if skin irritation persists.

Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Ingestion Rinse out mouth and give plenty of water to drink. In the event of symptoms seek medical treatment.

4.2 Most important symptoms and effects, both acute and delayed

None known.

4.3 Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Product itself is non-combustible. Fire extinguishing method of surrounding areas must be considered.

Extinguishing media that must not Full water jet be used

5.2 Special hazards arising from the substance or mixture

Risk of formation of toxic pyrolysis products.

5.3 Advice for firefighters

Use self-contained breathing apparatus.

Fire residues and contaminated firefighting water must be disposed of in accordance within the local regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Avoid dust formation. Use breathing apparatus if exposed to dust.

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Page 3

Safety Data Sheet (UK REACH) (GB) ACTILOX®, APYRAL® AOH

Nabaltec AG 92409 Schwandorf

Date printed 30.05.2022, Revision 30.05.2022 Version 02. Supersedes version: 01 Page 3 / 10

6.2 Environmental precautions

Do not discharge into the drains/surface waters/groundwater.

6.3 Methods and material for containment and cleaning up

Take up mechanically. Avoid production of dust. Dispose of absorbed material in accordance within the regulations.

6.4 Reference to other sections

See SECTION 8+13

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Avoid the formation and deposition of dust. Provide vacuuming if dust raised.

Use barrier skin cream. Wash hands before breaks and after work. Do not eat, drink, smoke or take drugs at work. Take off contaminated clothing and wash before reuse.

7.2 Conditions for safe storage, including any incompatibilities

Keep only in original container. Prevent penetration into the ground.

Do not store together with food and animal food/diet.

Store in a dry place.

7.3 Specific end use(s)

See product use, SECTION 1.2

SECTION 8: Exposure controls / personal protection

8.1 Control parameters

Ingredients with occupational exposure limits to be monitored (GB)

not applicable

DNEL

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

Industrial, inhalative, Long-term - local effects, 3.59 mg/m³

general population, oral, Long-term - systemic effects, 2.37 mg/kg bw/day

PNEC

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

freshwater, 74.9 µg/L

sewage treatment plants (STP), 20 mg/L

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Page 4

Safety Data Sheet (UK REACH) (GB) ACTILOX®, APYRAL® AOH

Nabaltec AG 92409 Schwandorf

Date printed 30.05.2022, Revision 30.05.2022 Version 02. Supersedes version: 01 Page 4 / 10

8.2 Exposure controls

Additional advice on system design Ensure adequate ventilation on workstation. Pay attention to dust limit value (ACGIH-2011: 10 mg/m³ particle inhalable; 3 mg/m³ particle respirable). Measurement methods for taking workplace measurements must meet the performance requirements of DIN EN 482. For example, recommendations are given in the IFA's list of hazardous substances.

Eye protection safety glasses

Hand protection 0.11 mm Nitrile rubber, >480 min (EN 374-1/-2/-3). The details concerned are recommendations. Please contact the glove supplier for further information.

Skin protection Protective clothing (EN 340)

Other Avoid contact with eyes. Do not inhale dust.

Respiratory protection In the event of occupational exposure limits being exceeded or of inadequate ventilation: wear appropriate respiratory protection. Short term: filter apparatus, filter P2. (DIN EN 143)

Thermal hazards none

Delimitation and monitoring of the Protect the environment by applying appropriate control measures to prevent or limit environmental exposition emissions.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state powder

Color white

Odor odourless

Odour threshold not applicable

pH-value 9 - 10 (20 °C / 68.0 °F) Saturated solution

pH-value [1%] not determined

Boiling point [°C] not applicable

Flash point [°C] not applicable

Flammability (solid, gas) [°C] no

Lower explosion limit not applicable

Upper explosion limit not applicable

Oxidising properties no

Vapour pressure/gas pressure [kPa] not applicable

Density [g/cm³] 3.0 (20 °C / 68,0 °F)

Relative density not determined

Bulk density [kg/m³] not determined

Solubility in water < 0.00009 g/l (20 °C) virtually insoluble

Solubility other solvents No information available.

Partition coefficient [n-octanol/water] not applicable

Kinematic viscosity not applicable

Relative vapour density not applicable

Evaporation speed not applicable

Melting point [°C] Decomposition

Auto-ignition temperature not self-igniting

Decomposition temperature [°C] > 340 °C

Particle characteristics not applicable

9.2 Other information

none

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Page 5

Safety Data Sheet (UK REACH) (GB) ACTILOX®, APYRAL® AOH

Nabaltec AG 92409 Schwandorf

Date printed 30.05.2022, Revision 30.05.2022 Version 02. Supersedes version: 01 Page 5 / 10

SECTION 10: Stability and reactivity

10.1 Reactivity

No dangerous reactions known if used as directed.

10.2 Chemical stability

Stable up to decomposition temperature.

10.3 Possibility of hazardous reactions

No hazardous reactions known.

10.4 Conditions to avoid

Strong heating. Decomposes begins at 340 °C.

10.5 Incompatible materials

Strong acids. Alkalies

10.6 Hazardous decomposition products

No hazardous decomposition products known.

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Page 6

Safety Data Sheet (UK REACH) (GB) ACTILOX®, APYRAL® AOH

Nabaltec AG 92409 Schwandorf

Date printed 30.05.2022, Revision 30.05.2022 Version 02. Supersedes version: 01 Page 6 / 10

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute oral toxicity

Product

ATE-mix, oral, > 2000 mg/kg

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

LD50, oral, Rat, > 2000 mg/kg bw

NOAEL, oral, Rat, 30 mg/kg bw/day chronic (analogon)

Acute dermal toxicity

Product

ATE-mix, dermal, > 2000 mg/kg

Acute inhalational toxicity

Product

ATE-mix, inhalativ (dust), > 5 mg/l 4h

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

LC50, inhalative, Rat, 7.6 mg/l 4h

NOAEC, inhalative, Rat, 70 mg/m³ subchronic (analogon)

Serious eye damage/irritation Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

Eye, non-irritating

Skin corrosion/irritation Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

dermal, non-irritating

Respiratory or skin sensitisation Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

inhalative, non-sensitizing

dermal, non-sensitizing

Specific target organ toxicity — Does not contain a relevant substance that meets the classification criteria. single exposure Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Substance

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Page 7

Safety Data Sheet (UK REACH) (GB) ACTILOX®, APYRAL® AOH

Nabaltec AG 92409 Schwandorf

Date printed 30.05.2022, Revision 30.05.2022 Version 02. Supersedes version: 01 Page 7 / 10

Boehmite (Al(OH)O), CAS: 1318-23-6

inhalative, non-irritating

Specific target organ toxicity — Does not contain a relevant substance that meets the classification criteria. repeated exposure Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

inhalative, no adverse effect observed

oral, no adverse effect observed

Mutagenicity Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Reproduction toxicity Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Carcinogenicity Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Aspiration hazard Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled.

General remarks

none

11.2 Information on other hazards

Endocrine disrupting properties Contains no ingredients with endocrine-disrupting properties.

Other information

SECTION 12: Ecological information

12.1 Toxicity

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

LC50, Salmo trutta, > 100 mg/l

EC50, Daphnia magna, > 100 mg/l

EC50, Selenastrum capricornutum, > 100 mg/l

12.2 Persistence and degradability

Behaviour in environment not determined compartments

Behaviour in sewage plant not determined

Biological degradability not determined

12.3 Bioaccumulative potential

Accumulation in organisms is not expected.

12.4 Mobility in soil

not applicable

12.5 Results of PBT and vPvB assessment

Based on all available information not to be classified as PBT or vPvB respectively.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 220519 nbc00050 GB

Page 8

Safety Data Sheet (UK REACH) (GB) ACTILOX®, APYRAL® AOH

Nabaltec AG 92409 Schwandorf

Date printed 30.05.2022, Revision 30.05.2022 Version 02. Supersedes version: 01 Page 8 / 10

12.6 Endocrine disrupting properties

Contains no ingredients with endocrine-disrupting properties.

12.7 Other adverse effects

None known.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison with the waste-disposal operator.

Product

For recycling, consult manufacturer.

Waste no. (recommended) 061399

Contaminated packaging

Uncontaminated packaging may be reused. Uncontaminated packaging may be taken for recycling.

Waste no. (recommended) 150101 150102

SECTION 14: Transport information

14.1 UN number or ID number

Transport by land according to not applicable ADR/RID

Inland navigation (ADN) not applicable

Marine transport in accordance with not applicable IMDG

Air transport in accordance with IATA not applicable

14.2 UN proper shipping name

Transport by land according to NO DANGEROUS GOODS ADR/RID

Inland navigation (ADN) NO DANGEROUS GOODS

Marine transport in accordance with NOT CLASSIFIED AS "DANGEROUS GOODS" IMDG

Air transport in accordance with IATA NOT CLASSIFIED AS "DANGEROUS GOODS"

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 220519 nbc00050 GB

Page 9

Safety Data Sheet (UK REACH) (GB) ACTILOX®, APYRAL® AOH

Nabaltec AG 92409 Schwandorf

Date printed 30.05.2022, Revision 30.05.2022 Version 02. Supersedes version: 01 Page 9 / 10

14.3 Transport hazard class(es)

Transport by land according to not applicable ADR/RID

Inland navigation (ADN) not applicable

Marine transport in accordance with not applicable IMDG

Air transport in accordance with IATA not applicable

14.4 Packing group

Transport by land according to not applicable ADR/RID

Inland navigation (ADN) not applicable

Marine transport in accordance with not applicable IMDG

Air transport in accordance with IATA not applicable

14.5 Environmental hazards

Transport by land according to no ADR/RID

Inland navigation (ADN) no

Marine transport in accordance with no IMDG

Air transport in accordance with IATA no

14.6 Special precautions for user

Relevant information under SECTION 6 to 8.

14.7 Maritime transport in bulk according to IMO instruments

not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EEC-REGULATIONS 2008/98/EC 2000/532/EC); 2010/75/EU; 2004/42/EC; (EC) 648/2004; (EC) 1907/2006 (REACH); (EU) 1272/2008; 75/324/EEC ((EC) 2016/2037); (EU) 2020/878; (EU) 2016/131; (EU) 517/2014

TRANSPORT-REGULATIONS ADR (2021); IMDG-Code (2021, 40. Amdt.); IATA-DGR (2022)

NATIONAL REGULATIONS (GB): EH40/2005 Workplace exposure limits (Second edition, published December 2011); UK REACH; GB CLP.

- Observe employment restrictions no for people

- VOC (2010/75/CE) 0 %

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Page 10

Safety Data Sheet (UK REACH) (GB) ACTILOX®, APYRAL® AOH

Nabaltec AG 92409 Schwandorf

Date printed 30.05.2022, Revision 30.05.2022 Version 02. Supersedes version: 01 Page 10 / 10

15.2 Chemical safety assessment

not applicable

SECTION 16: Other information

16.1 Abbreviations and acronyms:

ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route RID = Règlement concernant le transport international ferroviaire de marchandises dangereuses ADN = Accord européen relatif au transport international des marchandises dangereuses par voie de navigation intérieure ATE = acute toxicity estimate CAS = Chemical Abstracts Service CLP = Classification, Labelling and Packaging DMEL = Derived Minimum Effect Level DNEL = Derived No Effect Level EC50 = Median effective concentration ECB = European Chemicals Bureau EEC = European Economic Community EINECS = European Inventory of Existing Commercial Chemical Substances EL50 = Median effective loading ELINCS = European List of Notified Chemical Substances EmS = Emergency Schedules GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC-Code = International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk IC50 = Inhibition concentration, 50% IMDG = International Maritime Code for Dangerous Goods IUCLID = International Uniform ChemicaL Information Database IVIS = In vitro irritation score LC50 = Lethal concentration, 50% LD50 = Median lethal dose LC0 = lethal concentration, 0% LOAEL = lowest-observed-adverse-effect level LL50 = Median lethal loading LQ = Limited Quantities MARPOL = International Convention for the Prevention of Marine Pollution from Ships NOAEL = No Observed Adverse Effect Level NOEC = No Observed Effect Concentration PBT = Persistent, Bioaccumulative and Toxic substance PNEC = Predicted No-Effect Concentration REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals STP = Sewage Treatment Plant TLV®/TWA = Threshold limit value – time-weighted average TLV®STEL = Threshold limit value – short-time exposure limit VOC = Volatile Organic Compounds vPvB = very Persistent and very Bioaccumulative

16.2 Other information

Classification procedure

Modified position SECTION 2 been added: Contains no ingredients with endocrine-disrupting properties.

SECTION 8 been added: Short term: filter apparatus, filter P2. (DIN EN 143)

SECTION 8 been added: In the event of occupational exposure limits being exceeded or of

inadequate ventilation: wear appropriate respiratory protection.

Copyright: Chemiebüro®

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Modified surface — Safety Data Sheet — Nabaltec AG

Full document text

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

SECTION 2: Hazards identification

2.3 Other hazards

SECTION 3: Composition / Information on ingredients

SECTION 4: First aid measures

SECTION 5: Fire-fighting measures

SECTION 6: Accidental release measures

SECTION 7: Handling and storage

SECTION 8: Exposure controls / personal protection

8.2 Exposure controls

SECTION 9: Physical and chemical properties

9.2 Other information

SECTION 10: Stability and reactivity

10.6 Hazardous decomposition products

SECTION 11: Toxicological information

SECTION 12: Ecological information

12.7 Other adverse effects

SECTION 13: Disposal considerations

SECTION 14: Transport information

14.3 Transport hazard class(es)

SECTION 15: Regulatory information

SECTION 16: Other information

16.2 Other information

SECTION 8 been added: Short term: filter apparatus, filter P2. (DIN EN 143)

SECTION 8 been added: In the event of occupational exposure limits being exceeded or of