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SIBOM Creation date: 31.03.2020 , Revision: 25.08.2023 , Version: 1.4 — Safety Data Sheet — /UNDERTAKING

Original PDF document published by /UNDERTAKING.

Publisher
/UNDERTAKING
Document type
SDS
Material
SIBOM Creation date: 31.03.2020 , Revision: 25.08.2023 , Version: 1.4
CAS
1318-23-6
Product code
Not stated
Language
English
Revision
25.08.2023 · Version 1.4
Region
European Union · REACH / CLP
Pages
13
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Page 1

SAFETY DATA SHEET ACCORDING TO REGULATION (EC) 1907/2006 Product name: SIBOM® Creation date: 31.03.2020, Revision: 25.08.2023, Version: 1.4

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1 Product identifier

Product name SIBOM ®

Name: Boehmite (CAS: 1318-23-6, EC: 215-284-3) REACH Registration number: 01-2119555298-28-0018 https://my.chemius.net /p/Aptya9/en/pd/en Synonyms

The product names refer to additional codes representing different material grades:

SIBOM P84, SIBOM P84-VLS, SIBOM MP-84-1, SIBOM MP-84-2, SIBOM MP84-1-VLS, SIBOM

MP84-2-VLS, SIBOM P76

1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses

Additive, flame retardant, filler, catalyst, ceramics industry

Uses advised against

No information.

1.3 Details of the supplier of the safety data sheet Manufacturer

SILKEM, d. o. o. Tovarniška cesta 10 2325 Kidričevo, Slovenia +386 2 7991 200 info@silkem.si

1.4 Emergency Telephone Number Emergency

112

Manufacturer

+386 2 7991 208 (7h - 15h)

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 (CLP)

According to the regulation, the chemical is not classified as hazardous.

2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 [CLP]

Hazard statements:

Not applicable.

Supplemental hazard information (EU):

Not applicable.

Precautionary statements:

Not applicable.

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Page 2

SAFETY DATA SHEET ACCORDING TO REGULATION (EC) 1907/2006 Product name: SIBOM® Creation date: 31.03.2020, Revision: 25.08.2023, Version: 1.4

Special provisions

The product is not classified as dangerous according to regulations.

2.3 Other hazards

PBT/vPvB

No information.

Endocrine disrupting properties

The product does not contain substances with the potential for endocrine disorders.

Additional information

The substances in the product are not classified as persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB).

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances

Classification Specific CAS EC Index according to Notes for Name % Concentration Reach Regulation (EC) No substances Limits 1272/2008 (CLP)

1318-23-6 215-284-3 Boehmite - >99 / / / 01-2119555298- 28-0018

3.2 Mixtures For substances see 3.1.

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures General notes

When in doubt or if feeling unwell seek medical assistance. Never give anything by mouth to an unconscious person. Place patient in recovery position and ensure airway patency.

Following inhalation

Remove patient to fresh air - move out of dangerous area. If symptoms develop and persist, seek medical attention.

Following skin contact

Take off all contaminated clothing. If symptoms develop and persist, seek medical attention. Areas of the body that have come into contact with the product must be rinsed with water. Wash contaminated clothes and shoes before reuse.

Following eye contact

Immediately flush eyes with running water, keeping eyelids apart. If irritation persists, seek professional medical attention.

Following ingestion

Do not induce vomiting! Rinse mouth thoroughly with water. In case of doubt or if feeling unwell seek medical help. Show the physician the safety data sheet or label.

4.2 Most important symptoms and effects, both acute and delayed Following inhalation

No information.

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SAFETY DATA SHEET ACCORDING TO REGULATION (EC) 1907/2006 Product name: SIBOM® Creation date: 31.03.2020, Revision: 25.08.2023, Version: 1.4

Following skin contact

No information.

Following eye contact

No information.

Following ingestion

No information.

4.3 Indication of any immediate medical attention and special treatment needed Treat symptomatically.

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media Suitable extinguishing media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media

Full water jet.

5.2 Special hazards arising from the substance or mixture Hazardous combustion products

No information.

5.3 Advice for firefighters Protective actions

No information.

Special protective equipment for fire-fighters

In case of fire: Wear suitable respiratory equipment - self-contained breathing apparatus and full protective equipment.

Additional information

Contaminated firefighting water and fire residues must be disposed of in accordance with the local regulations.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel

Protective equipment

Use personal protective equipment (Section 8). Do not breathe dust.

Precautionary measures

Ensure adequate ventilation.

Emergency procedures

No information.

For emergency responders

No information.

6.2 Environmental precautions Do not allow product to reach water/drains/sewage systems or permeable soil.

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Page 4

SAFETY DATA SHEET ACCORDING TO REGULATION (EC) 1907/2006 Product name: SIBOM® Creation date: 31.03.2020, Revision: 25.08.2023, Version: 1.4

6.3 Methods and material for containment and cleaning up For containment

Prevent spillage - close holes on damaged container.

For cleaning up

Take up mechanically and collect in suitable container and dispose according to current regulations.

Other information

No information.

6.4 Reference to other sections See also sections 8 and 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling Protective measures

Measures to prevent fire

Ensure adequate ventilation.

Measures to prevent aerosol and dust generation

Prevent dust formation.

Measures to protect the environment

No information.

Other measures

No information.

Advice on general occupational hygiene

Use good personal hygiene practices – wash hands at breaks and when done working with material. Do not eat, drink or smoke while working. Do not breathe dust. Use personal protective equipment.

7.2 Conditions for safe storage, including any incompatibilities Technical measures and storage conditions

Keep in cool and well ventilated area. Keep in a dry place. Keep away from moisture. Keep away from food, drink and animal feeding stuffs.

Packaging materials

No information.

Requirements for storage rooms and vessels

No information.

Storage class

No information.

Further information on storage conditions

No information.

7.3 Specific end use(s) Recommendations

See identified uses in Section 1.2.

Industrial sector specific solutions

No information.

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Page 5

SAFETY DATA SHEET ACCORDING TO REGULATION (EC) 1907/2006 Product name: SIBOM® Creation date: 31.03.2020, Revision: 25.08.2023, Version: 1.4

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters Occupational Exposure limit values

No information.

Information on monitoring procedures

BS EN 14042:2003 Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents.BS EN 689:2018 Workplace exposure. Measurement of exposure by inhalation to chemical agents. Strategy for testing compliance with occupational exposure limit values.BS EN 482:2021 Workplace exposure. Procedures for the determination of the concentration of chemical agents. Basic performance requirements.

DNEL/DMEL values

For product

No information.

For components

Name Type Exposure route exp. frequency Remark value

Boehmite Worker inhalation long term / 3.59 mg/m³

Boehmite Consumer oral long term / 2.37 mg/kg bw/day

PNEC values

For product

No information.

For components

Name Exposure route Remark value

Boehmite fresh water / 74.9 μg/l

Boehmite water treatment plant / 20 mg/L

8.2 Exposure controls

Appropriate engineering control

Substance/mixture related measures to prevent exposure during identified uses

Do not breathe dust.

Structural measures to prevent exposure

No information.

Organisational measures to prevent exposure

No information.

Technical measures to prevent exposure

Provide good ventilation and local exhaust in areas with increased concentration.

Personal protective equipment

Eye and face protection

If there is risk of splashing into eyes, wear safety glasses with side shields (BS EN ISO 16321-1:2022).

Hand protection

Protective gloves (EN 374).

Appropriate materials

No information

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SAFETY DATA SHEET ACCORDING TO REGULATION (EC) 1907/2006 Product name: SIBOM® Creation date: 31.03.2020, Revision: 25.08.2023, Version: 1.4

Skin protection

Cotton protective clothing and shoes that cover the entire foot (EN ISO 20345).

Respiratory protection

Not needed under normal use and adequate ventilation. In case of insufficient ventilation wear mask with filter P2.

Thermal hazards

No information.

Environmental exposure controls

Substance/mixture related measures to prevent exposure

No information.

Instruction measures to prevent exposure

No information.

Organisational measures to prevent exposure

No information.

Technical measures to prevent exposure

No information.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties Physical state

solid

Colour

white

Odour

no odour

Important health, safety and environmental information

Odour threshold No information.

Melting point/Freezing point > 300 °C

Boiling point or initial boiling point and boiling range No information.

Flammability (Not flammable.)

Lower and upper explosion limit (Not explosive.)

Flash point No information.

Auto-ignition temperature (Not self-igniting.)

Decomposition temperature > 340 °C

pH No information.

Viscosity No information.

Solubility No information.

Partition coefficient No information.

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SAFETY DATA SHEET ACCORDING TO REGULATION (EC) 1907/2006 Product name: SIBOM® Creation date: 31.03.2020, Revision: 25.08.2023, Version: 1.4

Vapour pressure No information.

Density and/or relative density Bulk density: 200 — 1100 kg/m3

Relative vapour density No information.

Particle characteristics No information.

9.2 Other information

Oxidising properties Not oxidising.

Explosive properties Product is not explosive.

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity Stable under normal conditions.

10.2 Chemical stability Product is stable under normal conditions of use, recommended handling and storage conditions.

10.3 Possibility of hazardous reactions No dangerous reactions occur under normal conditions of storage and use.

10.4 Conditions to avoid Avoid high temperatures. Boehmite decomposes at temperature > 340°C into water (H2O) and aluminum oxide (Al2O3) without melting.

10.5 Incompatible materials

Acids. Strong bases.

10.6 Hazardous decomposition products

Under normal use conditions no hazardous decomposition products are expected.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 (a) Acute toxicity

For components

Exposure Name Type Species Time value Method Remark route

> 2000 mg/kg Boehmite oral LD50 rat / / / bw

Boehmite inhalation LC50 rat 4 h 7.6 mg/l / /

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Page 8

SAFETY DATA SHEET ACCORDING TO REGULATION (EC) 1907/2006 Product name: SIBOM® Creation date: 31.03.2020, Revision: 25.08.2023, Version: 1.4

(b) Skin corrosion/irritation

For components

Name Species Time result Method Remark

Boehmite / / Non-irritant. / /

(c) Serious eye damage/irritation

For components

Name Exposure route Species Time result Method Remark

Boehmite / / / Non-irritant. / /

(d) Respiratory or skin sensitisation

For components

Name Exposure route Species Time result Method Remark

Boehmite - / / Not classified. / /

(e) (Germ cell) mutagenicity

For components

Name Type Species Time result Method Remark

Boehmite / / / Not mutagenic. / /

(f) Carcinogenicity

For components

Exposure Name Type Species Time value result Method Remark route

Boehmite / / / / / Negative / /

(g) Reproductive toxicity

For components

Reproductiv Name e toxicity Type Species Time value result Method Remark type

Boehmite / / / / / Negative. / /

Summary of evaluation of the CMR properties

No information.

(h) STOT-single exposure

No information.

(i) STOT-repeated exposure

For components

Exposure Name Type Species Time Exposure organ value result Method Remark route

Boehmit 30 mg/kg oral NOAEL rat / / / / / chronic e bw/day

Boehmit inhalatio 70 subchron NOAEL rat / / / / / e n mg/m3 ic

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SAFETY DATA SHEET ACCORDING TO REGULATION (EC) 1907/2006 Product name: SIBOM® Creation date: 31.03.2020, Revision: 25.08.2023, Version: 1.4

(j) Aspiration hazard

For components

Name result Method Remark

Boehmite No adverse effect observed. / /

Symptoms related to the physical, chemical and toxicological characteristics

No information.

Interactive effects

No information.

11.2 Information on other hazards Endocrine disrupting properties

The product does not contain substances with the potential for endocrine disorders.

Other information

No information.

SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity Acute (short-term) toxicity

For components

Exposure Name Type value Species organism Method Remark time

Oncorhynchus Boehmite LC50 100 mg/L 96 h fish / / mykiss

Pimephales Boehmite LC50 100 mg/L 96 h fish / / promelas

Daphnia Boehmite EC50 100 mg/L 48 h daphnia / / magna

Chronic (long-term) toxicity

No information.

12.2 Persistence and degradability Abiotic degradation, physical- and photo-chemical elimination

No information.

Biodegradation

No information.

12.3 Bioaccumulative potential Partition coefficient

No information.

Bioconcentration factor (BCF)

No information.

12.4 Mobility in soil Known or predicted distribution to environmental compartments

No information.

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SAFETY DATA SHEET ACCORDING TO REGULATION (EC) 1907/2006 Product name: SIBOM® Creation date: 31.03.2020, Revision: 25.08.2023, Version: 1.4

Surface tension

No information.

Adsorption/Desorption

No information.

12.5 Results of PBT and vPvB assessment The substance is not classified as persistent, toxic, or a substance that can accumulate (PBT) or very persistent and very bioaccumulative (vPvB) substance.

12.6 Endocrine disrupting properties The product does not contain substances with the potential for endocrine disorders.

12.7 Other adverse effects

No information.

12.8 Additional information No information.

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods Product / Packaging disposal

Waste chemical

Waste should be handled in accordance with local or national regulations.

Waste codes / waste designations according to LoW

No information.

Packaging

Dispose of according to current environmental regulations.

Waste codes / waste designations according to LoW

No information.

Waste treatment-relevant information

Disposal in accordance with the Rules on the management of waste.

Sewage disposal-relevant information

No information.

Other disposal recommendations

Comply with the applicable legislation.

SECTION 14: TRANSPORT INFORMATION

14.1 UN number or ID number

ADR/RID IMDG IATA ADN

Not dangerous according to Not dangerous according to Not dangerous according to Not dangerous according to transport regulations. transport regulations. transport regulations. transport regulations.

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SAFETY DATA SHEET ACCORDING TO REGULATION (EC) 1907/2006 Product name: SIBOM® Creation date: 31.03.2020, Revision: 25.08.2023, Version: 1.4

14.2 UN proper shipping name

ADR/RID IMDG IATA ADN

Not given/not applicable Not given/not applicable Not given/not applicable Not given/not applicable

14.3 Transport hazard class(es)

ADR/RID IMDG IATA ADN

Not given/not applicable Not given/not applicable Not given/not applicable Not given/not applicable

14.4 Packing group

ADR/RID IMDG IATA ADN

Not given/not applicable Not given/not applicable Not given/not applicable Not given/not applicable

14.5 Environmental hazards

ADR/RID IMDG IATA ADN

NO NO NO NO

14.6 Special precautions for user

ADR/RID IMDG IATA ADN

Limited quantities: Not Limited quantities: Not Limited quantities: Not given/not applicable given/not applicable given/not applicable

14.7 Maritime transport in bulk according to IMO instruments

ADR/RID IMDG IATA ADN

Not given/not applicable

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture - Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (including last amendment Commission Regulation (EU) 2020/878)

- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

Information according 2004/42/EC about limitation of emissions of volatile organic compounds (VOC-guideline)

not applicable

Ingredients according to Regulation (EC) No 648/2004 on detergents

No information.

Special instructions

No information.

15.2 Chemical Safety Assessment No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

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SAFETY DATA SHEET ACCORDING TO REGULATION (EC) 1907/2006 Product name: SIBOM® Creation date: 31.03.2020, Revision: 25.08.2023, Version: 1.4

SECTION 16: OTHER INFORMATION

Indication of changes

2.3 Other hazards 3.1 Substances 3.2 Mixtures 6.3 Methods and material for containment and cleaning up 8.2 Exposure

controls 9.1 Information on basic physical and chemical properties 9.2 Other information 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 11.2 Information on other hazards 12.6 Endocrine disrupting properties 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Key literature references and sources for data

No information.

Abbreviations and acronyms

ATE - Acute Toxicity Estimate ADR - Agreement concerning the International Carriage of Dangerous Goods by Road ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways CEN - European Committee for Standardisation C&L - Classification and Labelling CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008 CAS# - Chemical Abstracts Service number CMR - Carcinogen, Mutagen, or Reproductive Toxicant CSA - Chemical Safety Assessment CSR - Chemical Safety Report DMEL - Derived Minimal Effect Level DNEL - Derived No Effect Level DPD - Dangerous Preparations Directive 1999/45/EC DSD - Dangerous Substances Directive 67/548/EEC DU - Downstream User EC - European Community ECHA - European Chemicals Agency EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS) EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway) EEC - European Economic Community EINECS - European Inventory of Existing Commercial Substances ELINCS - European List of notified Chemical Substances EN - European Standard EQS - Environmental Quality Standard EU - European Union Euphrac - European Phrase Catalogue EWC - European Waste Catalogue (replaced by LoW – see below) GES - Generic Exposure Scenario GHS - Globally Harmonized System IATA - International Air Transport Association ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air IMDG - International Maritime Dangerous Goods IMSBC - International Maritime Solid Bulk Cargoes IT - Information Technology IUCLID - International Uniform Chemical Information Database IUPAC - International Union for Pure Applied Chemistry JRC - Joint Research Centre Kow - octanol-water partition coefficient LC50 - Lethal Concentration to 50 % of a test population LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose) LE - Legal Entity LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm) LR - Lead Registrant M/I - Manufacturer / Importer MS - Member States MSDS - Material Safety Data Sheet OC - Operational Conditions OECD - Organization for Economic Co-operation and Development OEL - Occupational Exposure Limit Page 12 of 13

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SAFETY DATA SHEET ACCORDING TO REGULATION (EC) 1907/2006 Product name: SIBOM® Creation date: 31.03.2020, Revision: 25.08.2023, Version: 1.4

OJ - Official Journal OR - Only Representative OSHA - European Agency for Safety and Health at work PBT - Persistent, Bioaccumulative and Toxic substance PEC - Predicted Effect Concentration PNEC(s) - Predicted No Effect Concentration(s) PPE - Personal Protection Equipment (Q)SAR - Qualitative Structure Activity Relationship REACH - Registration, Evaluation, Authorisation and Restriction of ChemicalsRegulation (EC) No 1907/2006 RID - Regulations concerning the International Carriage of Dangerous Goods by Rail RIP - REACH Implementation Project RMM - Risk Management Measure SCBA - Self-Contained Breathing Apparatus SDS - Safety data sheet SIEF - Substance Information Exchange Forum SME - Small and Medium sized Enterprises STOT - Specific Target Organ Toxicity (STOT) RE - Repeated Exposure (STOT) SE - Single Exposure SVHC - Substances of Very High Concern UN - United Nations vPvB - Very Persistent and Very Bioaccumulative

List of relevant H phrases

No information.

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