ACTILOX® PA - B2 — Safety Data Sheet — Nabaltec AG PAGE 1 Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2 Nabaltec AG 92409 Schwandorf Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 1 / 10 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier ACTILOX® PA - B2 1.2 Relevant identified uses of the substance or mixture and uses advised against 1.2.1 Relevant uses Flame retardant, additive, filler, processing aid 1.2.2 Uses advised against None known. 1.3 Details of the supplier of the safety data sheet Company Nabaltec AG Postfach 1860 92409 Schwandorf / GERMANY Phone +49 (0) 9431-53-0 Fax +49 (0) 9431-53-289 Homepage www.nabaltec.de E-mail info@nabaltec.de Address enquiries to Technical information info@nabaltec.de Safety Data Sheet sdb@chemiebuero.de 1.4 Emergency telephone number Company +49 (0)9431 53222 (24h) +49 (0)9431 530 (24h) SECTION 2: Hazards identification 2.1 Classification of the substance or mixture [REGULATION (EC) No 1272/2008] No classification. 2.2 Label elements Hazard pictograms Hazard statements none 2.3 Other hazards Physico-chemical hazards Accumulation of fine dust may entail the risk of a dust explosion in the presence of air. Human health dangers Prolonged and excessive contact can cause irritation of the respiratory tract. Environmental hazards Does not contain any PBT or vPvB substances. Other hazards Further hazards were not determined with the current level of knowledge. SECTION 3: Composition / Information on ingredients Product-type: 3.2 The product is a mixture. Range [%] Substance 70 - 99,5 Boehmite (Al(OH)O) CAS: 1318-23-6, EINECS/ELINCS: 215-284-3, Reg-No.: 01-2119555298-28-XXXX 0,1 - 30 Polysiloxane Comment on component parts No dangerous components. Substances of Very High Concern - SVHC: substances are not contained or are below 0.1%. www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB PAGE 2 Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2 Nabaltec AG 92409 Schwandorf Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 2 / 10 SECTION 4: First aid measures 4.1 Description of first aid measures General information Change powdered clothing. Inhalation Ensure supply of fresh air. In the event of symptoms seek medical treatment. Skin contact When in contact with the skin, clean with soap and water. Consult a doctor if skin irritation persists. Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion Rinse out mouth and give plenty of water to drink. In the event of symptoms seek medical treatment. 4.2 Most important symptoms and effects, both acute and delayed None known. 4.3 Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing media Product itself is non-combustible. Fire extinguishing method of surrounding areas must be considered. Extinguishing media that must not Full water jet be used 5.2 Special hazards arising from the substance or mixture High concentration of dust (> 250 g/m³) may lead to dust explosion in the presence of a source of ignition. Risk of formation of toxic pyrolysis products. 5.3 Advice for firefighters Use self-contained breathing apparatus. Fire residues and contaminated firefighting water must be disposed of in accordance within the local regulations. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Avoid dust formation. Use breathing apparatus if exposed to dust. Keep away from all sources of ignition. 6.2 Environmental precautions Do not discharge into the drains/surface waters/groundwater. 6.3 Methods and material for containment and cleaning up Take up mechanically. Avoid production of dust. Dispose of absorbed material in accordance within the regulations. 6.4 Reference to other sections See SECTION 8+13 www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB PAGE 3 Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2 Nabaltec AG 92409 Schwandorf Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 3 / 10 SECTION 7: Handling and storage 7.1 Precautions for safe handling Avoid the formation and deposition of dust. Provide vacuuming if dust raised. Keep away from all sources of ignition. Use barrier skin cream. Wash hands before breaks and after work. Do not eat, drink, smoke or take drugs at work. Take off contaminated clothing and wash before reuse. 7.2 Conditions for safe storage, including any incompatibilities Keep only in original container. Prevent penetration into the ground. Do not store together with food and animal food/diet. Keep container tightly closed. Store in a dry place. 7.3 Specific end use(s) See product use, SECTION 1.2 SECTION 8: Exposure controls / personal protection 8.1 Control parameters Ingredients with occupational exposure limits to be monitored (GB) not applicable DNEL Substance Boehmite (Al(OH)O), CAS: 1318-23-6 Industrial, inhalative, Long-term - local effects: 3,59 mg/m³. general population, oral, Long-term - systemic effects: 2,37 mg/kg bw/day. PNEC Substance Boehmite (Al(OH)O), CAS: 1318-23-6 freshwater, 74,9 µg/L. sewage treatment plants (STP), 20 mg/L. www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB PAGE 4 Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2 Nabaltec AG 92409 Schwandorf Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 4 / 10 8.2 Exposure controls Additional advice on system design Ensure adequate ventilation on workstation. Pay attention to dust limit value (ACGIH-2011: 10 mg/m³ particle inhalable; 3 mg/m³ particle respirable). Measurement methods for taking workplace measurements must meet the performance requirements of DIN EN 482. For example, recommendations are given in the IFA's list of hazardous substances. Eye protection safety glasses Hand protection 0,11 mm Nitrile rubber, >480 min (EN 374-1/-2/-3). The details concerned are recommendations. Please contact the glove supplier for further information. Skin protection Protective clothing (EN 340) Other Avoid contact with eyes. Do not inhale dust. Respiratory protection Respiratory protection mask in the event of high concentrations. Short term: filter apparatus, filter P2. (DIN EN 143) Thermal hazards none Delimitation and monitoring of the Protect the environment by applying appropriate control measures to prevent or limit environmental exposition emissions. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Form powder Color white Odor odourless Odour threshold not applicable pH-value 7 - 9 (20 °C / 68,0 °F) (aqueous suspension) pH-value [1%] not determined Boiling point [°C] not applicable Flash point [°C] not determined Flammability (solid, gas) [°C] not applicable Lower explosion limit 250 g /m³ Upper explosion limit not determined Oxidising properties no Vapour pressure/gas pressure [kPa] not applicable Density [g/ml] not determined Bulk density [kg/m³] 610 Solubility in water < 0,00009 g/l (20 °C) virtually insoluble Partition coefficient [n-octanol/water] not applicable Viscosity not applicable Relative vapour density determined not applicable in air Evaporation speed not applicable Melting point [°C] not applicable Autoignition temperature [°C] not self-igniting Decomposition temperature [°C] not determined 9.2 Other information Minimum ignition temperature of a dust layer: no glowing combustion until 450°C Flammability [combustion factor at 20°C, 100°C]: 3 Maximal explosion express pressure [22°C]: 5,9 bar Kst – value: 37 bar.m.s-1 Minimum ignition energy (with inductance): Emin > 2387mJ Minimum ignition temperature of a dust cloud: 620°C www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB PAGE 5 Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2 Nabaltec AG 92409 Schwandorf Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 5 / 10 SECTION 10: Stability and reactivity 10.1 Reactivity No dangerous reactions known if used as directed. 10.2 Chemical stability Stable up to decomposition temperature. 10.3 Possibility of hazardous reactions Accumulation of fine dust may entail the risk of a dust explosion in the presence of air. 10.4 Conditions to avoid Strong heating. 10.5 Incompatible materials Strong acids. Strong bases. Strong oxidizing agent. 10.6 Hazardous decomposition products No hazardous decomposition products known. www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB PAGE 6 Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2 Nabaltec AG 92409 Schwandorf Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 6 / 10 SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Product ATE-mix, inhalativ (dust), > 5 mg/l 4h. ATE-mix, dermal, > 2000 mg/kg. ATE-mix, oral, > 2000 mg/kg. Substance Boehmite (Al(OH)O), CAS: 1318-23-6 LD50, oral, Rat: > 2000 mg/kg bw. LC50, inhalative, Rat: 7,6 mg/l 4h. NOAEL, oral, Rat: 30 mg/kg bw/day chronic (analogon). NOAEC, inhalative, Rat: 70 mg/m³ subchronic (analogon). Serious eye damage/irritation Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available. Skin corrosion/irritation Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available. Respiratory or skin sensitisation Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available. Specific target organ toxicity — Does not contain a relevant substance that meets the classification criteria. single exposure Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available. Specific target organ toxicity — Does not contain a relevant substance that meets the classification criteria. repeated exposure Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available. Mutagenicity Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available. Reproduction toxicity Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available. Carcinogenicity Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available. Aspiration hazard Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. General remarks none SECTION 12: Ecological information 12.1 Toxicity Substance Boehmite (Al(OH)O), CAS: 1318-23-6 LC50, Salmo trutta: > 100 mg/l. EC50, Daphnia magna: > 100 mg/l. EC50, Selenastrum capricornutum: > 100 mg/l. www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB PAGE 7 Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2 Nabaltec AG 92409 Schwandorf Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 7 / 10 12.2 Persistence and degradability Behaviour in environment not determined compartments Behaviour in sewage plant not determined Biological degradability not determined 12.3 Bioaccumulative potential Accumulation in organisms is not expected. 12.4 Mobility in soil not applicable 12.5 Results of PBT and vPvB assessment Based on all available information not to be classified as PBT or vPvB respectively. 12.6 Other adverse effects None known. SECTION 13: Disposal considerations 13.1 Waste treatment methods Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison with the waste-disposal operator. Product For recycling, consult manufacturer. Waste no. (recommended) 061399 Contaminated packaging Uncontaminated packaging may be reused. Uncontaminated packaging may be taken for recycling. Waste no. (recommended) 150101 150102 SECTION 14: Transport information 14.1 UN number Transport by land according to not applicable ADR/RID Inland navigation (ADN) not applicable Marine transport in accordance with not applicable IMDG Air transport in accordance with IATA not applicable www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB PAGE 8 Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2 Nabaltec AG 92409 Schwandorf Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 8 / 10 14.2 UN proper shipping name Transport by land according to NO DANGEROUS GOODS ADR/RID Inland navigation (ADN) NO DANGEROUS GOODS Marine transport in accordance with NOT CLASSIFIED AS "DANGEROUS GOODS" IMDG Air transport in accordance with IATA NOT CLASSIFIED AS "DANGEROUS GOODS" 14.3 Transport hazard class(es) Transport by land according to not applicable ADR/RID Inland navigation (ADN) not applicable Marine transport in accordance with not applicable IMDG Air transport in accordance with IATA not applicable 14.4 Packing group Transport by land according to not applicable ADR/RID Inland navigation (ADN) not applicable Marine transport in accordance with not applicable IMDG Air transport in accordance with IATA not applicable 14.5 Environmental hazards Transport by land according to no ADR/RID Inland navigation (ADN) no Marine transport in accordance with no IMDG Air transport in accordance with IATA no 14.6 Special precautions for user Relevant information under SECTION 6 to 8. 14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code not applicable www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB PAGE 9 Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2 Nabaltec AG 92409 Schwandorf Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 9 / 10 SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EEC-REGULATIONS 2008/98/EC 2000/532/EC); 2010/75/EU; 2004/42/EC; (EC) 648/2004; (EC) 1907/2006 (REACH); (EU) 1272/2008; 75/324/EEC ((EC) 2016/2037); (EU) 2015/830; (EU) 2016/131; (EU) 517/2014 TRANSPORT-REGULATIONS ADR (2019); IMDG-Code (2019, 39. Amdt.); IATA-DGR (2020) NATIONAL REGULATIONS (GB): EH40/2005 Workplace exposure limits (Second edition, published December 2011). - Observe employment restrictions no for people - VOC (2010/75/CE) not determined 15.2 Chemical safety assessment not applicable SECTION 16: Other information 16.1 Abbreviations and acronyms: ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route RID = Règlement concernant le transport international ferroviaire de marchandises dangereuses ADN = Accord européen relatif au transport international des marchandises dangereuses par voie de navigation intérieure ATE = acute toxicity estimate CAS = Chemical Abstracts Service CLP = Classification, Labelling and Packaging DMEL = Derived Minimum Effect Level DNEL = Derived No Effect Level EC50 = Median effective concentration ECB = European Chemicals Bureau EEC = European Economic Community EINECS = European Inventory of Existing Commercial Chemical Substances EL50 = Median effective loading ELINCS = European List of Notified Chemical Substances EmS = Emergency Schedules GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC-Code = International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk IC50 = Inhibition concentration, 50% IMDG = International Maritime Code for Dangerous Goods IUCLID = International Uniform ChemicaL Information Database LC50 = Lethal concentration, 50% LD50 = Median lethal dose LC0 = lethal concentration, 0% LOAEL = lowest-observed-adverse-effect level LL50 = Median lethal loading LQ = Limited Quantities MARPOL = International Convention for the Prevention of Marine Pollution from Ships NOAEL = No Observed Adverse Effect Level NOEC = No Observed Effect Concentration PBT = Persistent, Bioaccumulative and Toxic substance PNEC = Predicted No-Effect Concentration REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals STP = Sewage Treatment Plant TLV®/TWA = Threshold limit value – time-weighted average TLV®STEL = Threshold limit value – short-time exposure limit VOC = Volatile Organic Compounds vPvB = very Persistent and very Bioaccumulative 16.2 Other information Classification procedure www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB PAGE 10 Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2 Nabaltec AG 92409 Schwandorf Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 10 / 10 Modified position SECTION 2 been added: Accumulation of fine dust may entail the risk of a dust explosion in the presence of air. SECTION 5 been added: High concentration of dust (> 250 g/m³) may lead to dust explosion in the presence of a source of ignition. SECTION 9 been added: Minimum ignition temperature of a dust cloud: 620°C SECTION 9 been added: Minimum ignition energy (with inductance): Emin > 2387mJ SECTION 9 been added: Kst – value: 37 bar.m.s-1 SECTION 9 been added: Maximal explosion express pressure [22°C]: 5,9 bar SECTION 9 been added: Flammability [combustion factor at 20°C, 100°C]: 3 SECTION 9 been added: Minimum ignition temperature of a dust layer: no glowing combustion until 450°C SECTION 9 been added: not self-igniting SECTION 10 been added: Accumulation of fine dust may entail the risk of a dust explosion in the presence of air. Copyright: Chemiebüro® www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB