APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM — Safety Data Sheet — Nabaltec AG PAGE 1 Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM Nabaltec AG 92409 Schwandorf Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 1 / 11 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Valid for all product variants Registration number 01-2119555298-28-XXXX IUPAC Boehmite (Al(OH)O) EINECS/ELINCS 215-284-3 CAS 1318-23-6 1.2 Relevant identified uses of the substance or mixture and uses advised against 1.2.1 Relevant uses Flame retardant, additive, filler, pigment, ground chemical, health care, personal care, viscosity adjustor 1.2.2 Uses advised against None known. 1.3 Details of the supplier of the safety data sheet Company Nabaltec AG Postfach 1860 92409 Schwandorf / GERMANY Phone +49 (0) 9431-53-0 Fax +49 (0) 9431-53-289 Homepage www.nabaltec.de E-mail info@nabaltec.de Address enquiries to Technical information info@nabaltec.de Safety Data Sheet sdb@chemiebuero.de (No dispatch of safety data sheets) Safety data sheets are available from the supplier. 1.4 Emergency telephone number Company +49 (0)9431 53222 (24h) +49 (0)9431 530 (24h) SECTION 2: Hazards identification 2.1 Classification of the substance or mixture [REGULATION (EC) No 1272/2008] No classification. 2.2 Label elements Hazard pictograms Hazard statements none 2.3 Other hazards Physico-chemical hazards not applicable Human health dangers Contains no ingredients with endocrine-disrupting properties. Environmental hazards Does not contain any PBT or vPvB substances. Other hazards none www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU PAGE 2 Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM Nabaltec AG 92409 Schwandorf Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 2 / 11 SECTION 3: Composition / Information on ingredients 3.1 Substances The product is a substance. Range [%] Substance >99 Boehmite (Al(OH)O) CAS: 1318-23-6, EINECS/ELINCS: 215-284-3, Reg-No.: 01-2119555298-28-XXXX Comment on component parts No dangerous components. Substances of Very High Concern - SVHC: substances are not contained or are below 0.1%. 3.2 Mixtures not applicable SECTION 4: First aid measures 4.1 Description of first aid measures General information Change powdered clothing. Inhalation Ensure supply of fresh air. In the event of symptoms seek medical treatment. Skin contact When in contact with the skin, clean with soap and water. Consult a doctor if skin irritation persists. Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion Rinse out mouth and give plenty of water to drink. In the event of symptoms seek medical treatment. 4.2 Most important symptoms and effects, both acute and delayed None known. 4.3 Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing media Product itself is non-combustible. Fire extinguishing method of surrounding areas must be considered. Extinguishing media that must not Full water jet. be used 5.2 Special hazards arising from the substance or mixture none 5.3 Advice for firefighters Use self-contained breathing apparatus. Fire residues and contaminated firefighting water must be disposed of in accordance within the local regulations. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Use breathing apparatus if exposed to dust. Avoid dust formation. Ensure adequate ventilation. www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU PAGE 3 Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM Nabaltec AG 92409 Schwandorf Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 3 / 11 6.2 Environmental precautions Do not discharge into the drains/surface waters/groundwater. 6.3 Methods and material for containment and cleaning up Take up mechanically. Avoid production of dust. Dispose of absorbed material in accordance within the regulations. 6.4 Reference to other sections See SECTION 8+13 SECTION 7: Handling and storage 7.1 Precautions for safe handling Avoid the formation and deposition of dust. Provide vacuuming if dust raised. Use only in well-ventilated areas. Wash hands before breaks and after work. Use barrier skin cream. 7.2 Conditions for safe storage, including any incompatibilities Keep only in original container. Prevent penetration into the ground. Do not store together with food and animal food/diet. Store in a dry place. 7.3 Specific end use(s) See product use, SECTION 1.2 SECTION 8: Exposure controls / personal protection 8.1 Control parameters Ingredients with occupational exposure limits to be monitored (EU) not relevant DNEL Substance Boehmite (Al(OH)O), CAS: 1318-23-6 Industrial, inhalative, Long-term - local effects, 3.59 mg/m³ general population, oral, Long-term - systemic effects, 2.37 mg/kg bw/day PNEC Substance Boehmite (Al(OH)O), CAS: 1318-23-6 freshwater, 74.9 µg/L sewage treatment plants (STP), 20 mg/L www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU PAGE 4 Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM Nabaltec AG 92409 Schwandorf Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 4 / 11 8.2 Exposure controls Additional advice on system design Ensure adequate ventilation on workstation. Pay attention to dust limit value (ACGIH-2011: 10 mg/m³ particle inhalable; 1,25 mg/m³ particle respirable). Measurement methods for taking workplace measurements must meet the performance requirements of DIN EN 482. For example, recommendations are given in the IFA's list of hazardous substances. Eye protection Safety glasses. (EN 166:2001) Hand protection 0.11mm Nitrile rubber, >480 min (EN 374-1/-2/-3). The details concerned are recommendations. Please contact the glove supplier for further information. Skin protection Protective clothing (EN 340) Other Do not inhale dust. Avoid contact with eyes and skin. Personal protective equipment should be selected specifically for the working place, depending on concentration and quantity handled. The resistance of this equipment to chemicals should be ascertained with the respective supplier. Respiratory protection In the event of occupational exposure limits being exceeded or of inadequate ventilation: wear appropriate respiratory protection. Short term: filter apparatus, filter P2. (DIN EN 143) Thermal hazards none Delimitation and monitoring of the Protect the environment by applying appropriate control measures to prevent or limit environmental exposition emissions. www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU PAGE 5 Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM Nabaltec AG 92409 Schwandorf Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 5 / 11 SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Physical state solid Form powder Color white Odor odourless Odour threshold not applicable pH-value 9 - 10 (20°C / 68°F) (aqueous suspension) pH-value [1%] not applicable Boiling point [°C] not relevant Flash point [°C] not applicable Flammability not applicable Lower explosion limit not applicable Upper explosion limit not applicable Oxidising properties no Vapour pressure/gas pressure [kPa] not applicable Density [g/cm³] 3.0 (20°C / 68°F) Relative density not determined Bulk density [kg/m³] not determined Solubility in water <0.00009 g/l (20°C / 68°F) Solubility other solvents not required Partition coefficient [n-octanol/water] not applicable Kinematic viscosity not applicable Relative vapour density not applicable Evaporation speed not applicable Melting point [°C] not relevant Auto-ignition temperature [°C] not self-igniting Decomposition temperature [°C] > 340°C / 644°F Particle characteristics not relevant 9.2 Other information none SECTION 10: Stability and reactivity 10.1 Reactivity No dangerous reactions known if used as directed. 10.2 Chemical stability The product is stable under standard conditions. 10.3 Possibility of hazardous reactions No hazardous reactions known. 10.4 Conditions to avoid Strong heating, because the thermal decomposition starts from 340°C / 644°F. www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU PAGE 6 Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM Nabaltec AG 92409 Schwandorf Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 6 / 11 10.5 Incompatible materials Acids Alkalies 10.6 Hazardous decomposition products No hazardous decomposition products known. www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU PAGE 7 Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM Nabaltec AG 92409 Schwandorf Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 7 / 11 SECTION 11: Toxicological information 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 Acute oral toxicity Substance Boehmite (Al(OH)O), CAS: 1318-23-6 LD50, oral, Rat, > 2000 mg/kg bw NOAEL, oral, Rat, 30 mg/kg bw/day chronic (analogon) Acute dermal toxicity Product Based on the available information, the classification criteria are not fulfilled. Acute inhalational toxicity Substance Boehmite (Al(OH)O), CAS: 1318-23-6 LC50, inhalative, Rat, 7.6 mg/l 4h NOAEC, inhalative, Rat, 70 mg/m³ subchronic (analogon) Serious eye damage/irritation Non-corrosive / non-irritating. Substance Boehmite (Al(OH)O), CAS: 1318-23-6 Eye, non-irritating Skin corrosion/irritation Non-corrosive / non-irritating. Substance Boehmite (Al(OH)O), CAS: 1318-23-6 dermal, non-irritating Respiratory or skin sensitisation Non-sensitizing. Substance Boehmite (Al(OH)O), CAS: 1318-23-6 inhalative, non-sensitizing dermal, non-sensitizing Specific target organ toxicity — No classification. single exposure Substance Boehmite (Al(OH)O), CAS: 1318-23-6 inhalative, non-irritating Specific target organ toxicity — No classification. repeated exposure Substance Boehmite (Al(OH)O), CAS: 1318-23-6 inhalative, no adverse effect observed oral, no adverse effect observed Mutagenicity There is no evidence of any mutagenic effects. www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU PAGE 8 Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM Nabaltec AG 92409 Schwandorf Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 8 / 11 Reproduction toxicity There is no evidence of any reproductive toxicity effects. Carcinogenicity There is no evidence of any carcinogenic effects. Aspiration hazard No classification. General remarks none 11.2 Information on other hazards Endocrine disrupting properties Contains no ingredients with endocrine-disrupting properties. Other information none SECTION 12: Ecological information 12.1 Toxicity Substance Boehmite (Al(OH)O), CAS: 1318-23-6 LC50, Salmo trutta, > 100 mg/l EC50, Daphnia magna, > 100 mg/l EC50, Selenastrum capricornutum, > 100 mg/l 12.2 Persistence and degradability Behaviour in environment not determined compartments Behaviour in sewage plant not determined Biological degradability not applicable 12.3 Bioaccumulative potential not applicable 12.4 Mobility in soil not determined 12.5 Results of PBT and vPvB assessment not applicable 12.6 Endocrine disrupting properties Contains no ingredients with endocrine-disrupting properties. 12.7 Other adverse effects None known. www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU PAGE 9 Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM Nabaltec AG 92409 Schwandorf Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 9 / 11 SECTION 13: Disposal considerations 13.1 Waste treatment methods Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison with the waste-disposal operator. Product For recycling, consult manufacturer. Waste no. (recommended) 061399 Contaminated packaging Uncontaminated packaging may be reused. Uncontaminated packaging may be taken for recycling. Waste no. (recommended) 150101 150102 SECTION 14: Transport information 14.1 UN number or ID number Transport by land according to not applicable ADR/RID Inland navigation (ADN) not applicable Marine transport in accordance with not applicable IMDG Air transport in accordance with IATA not applicable 14.2 UN proper shipping name Transport by land according to NO DANGEROUS GOODS ADR/RID Inland navigation (ADN) NO DANGEROUS GOODS Marine transport in accordance with NOT CLASSIFIED AS "DANGEROUS GOODS" IMDG Air transport in accordance with IATA NOT CLASSIFIED AS "DANGEROUS GOODS" 14.3 Transport hazard class(es) Transport by land according to not applicable ADR/RID Inland navigation (ADN) not applicable Marine transport in accordance with not applicable IMDG Air transport in accordance with IATA not applicable www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU PAGE 10 Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM Nabaltec AG 92409 Schwandorf Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 10 / 11 14.4 Packing group Transport by land according to not applicable ADR/RID Inland navigation (ADN) not applicable Marine transport in accordance with not applicable IMDG Air transport in accordance with IATA not applicable 14.5 Environmental hazards Transport by land according to no ADR/RID Inland navigation (ADN) no Marine transport in accordance with no IMDG Air transport in accordance with IATA no 14.6 Special precautions for user Relevant information under SECTION 6 to 8. 14.7 Maritime transport in bulk according to IMO instruments not applicable SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EEC-REGULATIONS 2008/98/EC 2000/532/EC); 2010/75/EU; 2004/42/EC; (EC) 648/2004; (EC) 1907/2006 (REACH); (EU) 1272/2008; 75/324/EEC ((EC) 2016/2037); (EU) 2020/878; (EU) 2016/131; (EU) 517/2014 TRANSPORT-REGULATIONS ADR (2023); IMDG-Code (2023, 41. Amdt.); IATA-DGR (2023) NATIONAL REGULATIONS (EU): - Observe employment restrictions no for people - VOC (2010/75/CE) 0 % 15.2 Chemical safety assessment For this substance a chemical safety assessment has been carried out. www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU PAGE 11 Safety Data Sheet according to REACH-Regulation (EC) 1907/2006 amended by regulation (EC) 2020/878 (EU) APYRAL AOH, APYRAL AOH BFG, ACTILOX AS, ACTILOX B, ACTILOX SM Nabaltec AG 92409 Schwandorf Date printed 11.04.2023, Revision 14.07.2022 Version 15.0. Supersedes version: 14.0 Page 11 / 11 SECTION 16: Other information 16.1 Abbreviations and acronyms: ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route RID = Règlement concernant le transport international ferroviaire de marchandises dangereuses ADN = Accord européen relatif au transport international des marchandises dangereuses par voie de navigation intérieure ATE = acute toxicity estimate CAS = Chemical Abstracts Service CLP = Classification, Labelling and Packaging DMEL = Derived Minimum Effect Level DNEL = Derived No Effect Level EC50 = Median effective concentration ECB = European Chemicals Bureau EEC = European Economic Community EINECS = European Inventory of Existing Commercial Chemical Substances EL50 = Median effective loading ELINCS = European List of Notified Chemical Substances EmS = Emergency Schedules GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC-Code = International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk IC50 = Inhibition concentration, 50% IMDG = International Maritime Code for Dangerous Goods IUCLID = International Uniform ChemicaL Information Database IVIS = In vitro irritation score LC50 = Lethal concentration, 50% LD50 = Median lethal dose LC0 = lethal concentration, 0% LOAEL = lowest-observed-adverse-effect level LL50 = Median lethal loading LQ = Limited Quantities MARPOL = International Convention for the Prevention of Marine Pollution from Ships NOAEL = No Observed Adverse Effect Level NOEC = No Observed Effect Concentration PBT = Persistent, Bioaccumulative and Toxic substance PNEC = Predicted No-Effect Concentration REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals STP = Sewage Treatment Plant TLV®/TWA = Threshold limit value – time-weighted average TLV®STEL = Threshold limit value – short-time exposure limit VOC = Volatile Organic Compounds vPvB = very Persistent and very Bioaccumulative 16.2 Other information Classification procedure Modified position none Copyright: Chemiebüro® www.chemiebuero.de, Phone +49 (0)941-646 353-0, 230403 nbc00009 EU