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ACTILOX® PA - B2 — Safety Data Sheet — Nabaltec AG

Flame retardant, additive, filler, processing aid

Publisher
Nabaltec AG
Document type
SDS
Material
ACTILOX® PA - B2
CAS
1318-23-6
Product code
Not stated
Language
English
Revision
20.05.2020 · Version 02
Region
European Union · REACH / CLP
Pages
10
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Page 1

Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2

Nabaltec AG 92409 Schwandorf

Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 1 / 10

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

ACTILOX® PA - B2

1.2 Relevant identified uses of the substance or mixture and uses advised against

1.2.1 Relevant uses Flame retardant, additive, filler, processing aid

1.2.2 Uses advised against None known.

1.3 Details of the supplier of the safety data sheet Company Nabaltec AG Postfach 1860 92409 Schwandorf / GERMANY Phone +49 (0) 9431-53-0 Fax +49 (0) 9431-53-289 Homepage www.nabaltec.de E-mail info@nabaltec.de

Address enquiries to Technical information info@nabaltec.de

Safety Data Sheet sdb@chemiebuero.de

1.4 Emergency telephone number Company +49 (0)9431 53222 (24h) +49 (0)9431 530 (24h)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture [REGULATION (EC) No 1272/2008] No classification.

2.2 Label elements

Hazard pictograms

Hazard statements none

2.3 Other hazards

Physico-chemical hazards Accumulation of fine dust may entail the risk of a dust explosion in the presence of air.

Human health dangers Prolonged and excessive contact can cause irritation of the respiratory tract.

Environmental hazards Does not contain any PBT or vPvB substances.

Other hazards Further hazards were not determined with the current level of knowledge.

SECTION 3: Composition / Information on ingredients

Product-type: 3.2 The product is a mixture.

Range [%] Substance

70 - 99,5 Boehmite (Al(OH)O) CAS: 1318-23-6, EINECS/ELINCS: 215-284-3, Reg-No.: 01-2119555298-28-XXXX 0,1 - 30 Polysiloxane

Comment on component parts No dangerous components. Substances of Very High Concern - SVHC: substances are not contained or are below 0.1%.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB

Page 2

Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2

Nabaltec AG 92409 Schwandorf

Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 2 / 10

SECTION 4: First aid measures

4.1 Description of first aid measures General information Change powdered clothing.

Inhalation Ensure supply of fresh air. In the event of symptoms seek medical treatment.

Skin contact When in contact with the skin, clean with soap and water. Consult a doctor if skin irritation persists.

Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Ingestion Rinse out mouth and give plenty of water to drink. In the event of symptoms seek medical treatment.

4.2 Most important symptoms and effects, both acute and delayed None known.

4.3 Indication of any immediate medical attention and special treatment needed Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media Suitable extinguishing media Product itself is non-combustible. Fire extinguishing method of surrounding areas must be considered.

Extinguishing media that must not Full water jet be used

5.2 Special hazards arising from the substance or mixture High concentration of dust (> 250 g/m³) may lead to dust explosion in the presence of a source of ignition. Risk of formation of toxic pyrolysis products.

5.3 Advice for firefighters Use self-contained breathing apparatus.

Fire residues and contaminated firefighting water must be disposed of in accordance within the local regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures Avoid dust formation. Use breathing apparatus if exposed to dust. Keep away from all sources of ignition.

6.2 Environmental precautions Do not discharge into the drains/surface waters/groundwater.

6.3 Methods and material for containment and cleaning up Take up mechanically. Avoid production of dust. Dispose of absorbed material in accordance within the regulations.

6.4 Reference to other sections See SECTION 8+13

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB

Page 3

Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2

Nabaltec AG 92409 Schwandorf

Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 3 / 10

SECTION 7: Handling and storage

7.1 Precautions for safe handling Avoid the formation and deposition of dust. Provide vacuuming if dust raised.

Keep away from all sources of ignition.

Use barrier skin cream. Wash hands before breaks and after work. Do not eat, drink, smoke or take drugs at work. Take off contaminated clothing and wash before reuse.

7.2 Conditions for safe storage, including any incompatibilities Keep only in original container. Prevent penetration into the ground.

Do not store together with food and animal food/diet.

Keep container tightly closed. Store in a dry place.

7.3 Specific end use(s) See product use, SECTION 1.2

SECTION 8: Exposure controls / personal protection

8.1 Control parameters Ingredients with occupational exposure limits to be monitored (GB)

not applicable

DNEL

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

Industrial, inhalative, Long-term - local effects: 3,59 mg/m³.

general population, oral, Long-term - systemic effects: 2,37 mg/kg bw/day.

PNEC

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

freshwater, 74,9 µg/L.

sewage treatment plants (STP), 20 mg/L.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB

Page 4

Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2

Nabaltec AG 92409 Schwandorf

Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 4 / 10

8.2 Exposure controls

Additional advice on system design Ensure adequate ventilation on workstation. Pay attention to dust limit value (ACGIH-2011: 10 mg/m³ particle inhalable; 3 mg/m³ particle respirable). Measurement methods for taking workplace measurements must meet the performance requirements of DIN EN 482. For example, recommendations are given in the IFA's list of hazardous substances.

Eye protection safety glasses

Hand protection 0,11 mm Nitrile rubber, >480 min (EN 374-1/-2/-3). The details concerned are recommendations. Please contact the glove supplier for further information.

Skin protection Protective clothing (EN 340)

Other Avoid contact with eyes. Do not inhale dust.

Respiratory protection Respiratory protection mask in the event of high concentrations. Short term: filter apparatus, filter P2. (DIN EN 143)

Thermal hazards none

Delimitation and monitoring of the Protect the environment by applying appropriate control measures to prevent or limit environmental exposition emissions.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties Form powder

Color white

Odor odourless

Odour threshold not applicable

pH-value 7 - 9 (20 °C / 68,0 °F) (aqueous suspension)

pH-value [1%] not determined

Boiling point [°C] not applicable

Flash point [°C] not determined

Flammability (solid, gas) [°C] not applicable

Lower explosion limit 250 g /m³

Upper explosion limit not determined

Oxidising properties no

Vapour pressure/gas pressure [kPa] not applicable

Density [g/ml] not determined

Bulk density [kg/m³] 610

Solubility in water < 0,00009 g/l (20 °C) virtually insoluble

Partition coefficient [n-octanol/water] not applicable

Viscosity not applicable

Relative vapour density determined not applicable in air

Evaporation speed not applicable

Melting point [°C] not applicable

Autoignition temperature [°C] not self-igniting

Decomposition temperature [°C] not determined

9.2 Other information

Minimum ignition temperature of a dust layer: no glowing combustion until 450°C Flammability [combustion factor at 20°C, 100°C]: 3 Maximal explosion express pressure [22°C]: 5,9 bar Kst – value: 37 bar.m.s-1 Minimum ignition energy (with inductance): Emin > 2387mJ Minimum ignition temperature of a dust cloud: 620°C

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB

Page 5

Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2

Nabaltec AG 92409 Schwandorf

Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 5 / 10

SECTION 10: Stability and reactivity

10.1 Reactivity

No dangerous reactions known if used as directed.

10.2 Chemical stability

Stable up to decomposition temperature.

10.3 Possibility of hazardous reactions

Accumulation of fine dust may entail the risk of a dust explosion in the presence of air.

10.4 Conditions to avoid

Strong heating.

10.5 Incompatible materials

Strong acids. Strong bases. Strong oxidizing agent.

10.6 Hazardous decomposition products

No hazardous decomposition products known.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB

Page 6

Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2

Nabaltec AG 92409 Schwandorf

Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 6 / 10

SECTION 11: Toxicological information

11.1 Information on toxicological effects Acute toxicity

Product

ATE-mix, inhalativ (dust), > 5 mg/l 4h.

ATE-mix, dermal, > 2000 mg/kg.

ATE-mix, oral, > 2000 mg/kg.

Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

LD50, oral, Rat: > 2000 mg/kg bw.

LC50, inhalative, Rat: 7,6 mg/l 4h.

NOAEL, oral, Rat: 30 mg/kg bw/day chronic (analogon).

NOAEC, inhalative, Rat: 70 mg/m³ subchronic (analogon).

Serious eye damage/irritation Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Skin corrosion/irritation Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Respiratory or skin sensitisation Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Specific target organ toxicity — Does not contain a relevant substance that meets the classification criteria. single exposure Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Specific target organ toxicity — Does not contain a relevant substance that meets the classification criteria. repeated exposure Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Mutagenicity Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Reproduction toxicity Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Carcinogenicity Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled. Toxicological data of complete product are not available.

Aspiration hazard Does not contain a relevant substance that meets the classification criteria. Based on the available information, the classification criteria are not fulfilled.

General remarks

none

SECTION 12: Ecological information

12.1 Toxicity Substance

Boehmite (Al(OH)O), CAS: 1318-23-6

LC50, Salmo trutta: > 100 mg/l.

EC50, Daphnia magna: > 100 mg/l.

EC50, Selenastrum capricornutum: > 100 mg/l.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB

Page 7

Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2

Nabaltec AG 92409 Schwandorf

Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 7 / 10

12.2 Persistence and degradability

Behaviour in environment not determined compartments

Behaviour in sewage plant not determined

Biological degradability not determined

12.3 Bioaccumulative potential

Accumulation in organisms is not expected.

12.4 Mobility in soil

not applicable

12.5 Results of PBT and vPvB assessment

Based on all available information not to be classified as PBT or vPvB respectively.

12.6 Other adverse effects

None known.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison with the waste-disposal operator.

Product For recycling, consult manufacturer.

Waste no. (recommended) 061399

Contaminated packaging Uncontaminated packaging may be reused. Uncontaminated packaging may be taken for recycling.

Waste no. (recommended) 150101 150102

SECTION 14: Transport information

14.1 UN number Transport by land according to not applicable ADR/RID

Inland navigation (ADN) not applicable

Marine transport in accordance with not applicable IMDG

Air transport in accordance with IATA not applicable

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB

Page 8

Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2

Nabaltec AG 92409 Schwandorf

Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 8 / 10

14.2 UN proper shipping name Transport by land according to NO DANGEROUS GOODS ADR/RID

Inland navigation (ADN) NO DANGEROUS GOODS

Marine transport in accordance with NOT CLASSIFIED AS "DANGEROUS GOODS" IMDG

Air transport in accordance with IATA NOT CLASSIFIED AS "DANGEROUS GOODS"

14.3 Transport hazard class(es)

Transport by land according to not applicable ADR/RID

Inland navigation (ADN) not applicable

Marine transport in accordance with not applicable IMDG

Air transport in accordance with IATA not applicable

14.4 Packing group Transport by land according to not applicable ADR/RID

Inland navigation (ADN) not applicable

Marine transport in accordance with not applicable IMDG

Air transport in accordance with IATA not applicable

14.5 Environmental hazards Transport by land according to no ADR/RID

Inland navigation (ADN) no

Marine transport in accordance with no IMDG

Air transport in accordance with IATA no

14.6 Special precautions for user

Relevant information under SECTION 6 to 8.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code

not applicable

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB

Page 9

Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2

Nabaltec AG 92409 Schwandorf

Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 9 / 10

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EEC-REGULATIONS 2008/98/EC 2000/532/EC); 2010/75/EU; 2004/42/EC; (EC) 648/2004; (EC) 1907/2006 (REACH); (EU) 1272/2008; 75/324/EEC ((EC) 2016/2037); (EU) 2015/830; (EU) 2016/131; (EU) 517/2014

TRANSPORT-REGULATIONS ADR (2019); IMDG-Code (2019, 39. Amdt.); IATA-DGR (2020)

NATIONAL REGULATIONS (GB): EH40/2005 Workplace exposure limits (Second edition, published December 2011).

- Observe employment restrictions no for people

- VOC (2010/75/CE) not determined

15.2 Chemical safety assessment not applicable

SECTION 16: Other information

16.1 Abbreviations and acronyms: ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route RID = Règlement concernant le transport international ferroviaire de marchandises dangereuses ADN = Accord européen relatif au transport international des marchandises dangereuses par voie de navigation intérieure ATE = acute toxicity estimate CAS = Chemical Abstracts Service CLP = Classification, Labelling and Packaging DMEL = Derived Minimum Effect Level DNEL = Derived No Effect Level EC50 = Median effective concentration ECB = European Chemicals Bureau EEC = European Economic Community EINECS = European Inventory of Existing Commercial Chemical Substances EL50 = Median effective loading ELINCS = European List of Notified Chemical Substances EmS = Emergency Schedules GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC-Code = International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk IC50 = Inhibition concentration, 50% IMDG = International Maritime Code for Dangerous Goods IUCLID = International Uniform ChemicaL Information Database LC50 = Lethal concentration, 50% LD50 = Median lethal dose LC0 = lethal concentration, 0% LOAEL = lowest-observed-adverse-effect level LL50 = Median lethal loading LQ = Limited Quantities MARPOL = International Convention for the Prevention of Marine Pollution from Ships NOAEL = No Observed Adverse Effect Level NOEC = No Observed Effect Concentration PBT = Persistent, Bioaccumulative and Toxic substance PNEC = Predicted No-Effect Concentration REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals STP = Sewage Treatment Plant TLV®/TWA = Threshold limit value – time-weighted average TLV®STEL = Threshold limit value – short-time exposure limit VOC = Volatile Organic Compounds vPvB = very Persistent and very Bioaccumulative

16.2 Other information

Classification procedure

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB

Page 10

Safety Data Sheet 1907/2006/EC - REACH (GB) ACTILOX® PA - B2

Nabaltec AG 92409 Schwandorf

Date printed 30.06.2020, Revision 20.05.2020 Version 02. Supersedes version: 01 Page 10 / 10

Modified position SECTION 2 been added: Accumulation of fine dust may entail the risk of a dust explosion in the presence of air.

SECTION 5 been added: High concentration of dust (> 250 g/m³) may lead to dust explosion

in the presence of a source of ignition.

SECTION 9 been added: Minimum ignition temperature of a dust cloud: 620°C

SECTION 9 been added: Minimum ignition energy (with inductance): Emin > 2387mJ

SECTION 9 been added: Kst – value: 37 bar.m.s-1

SECTION 9 been added: Maximal explosion express pressure [22°C]: 5,9 bar

SECTION 9 been added: Flammability [combustion factor at 20°C, 100°C]: 3

SECTION 9 been added: Minimum ignition temperature of a dust layer: no glowing

combustion until 450°C

SECTION 9 been added: not self-igniting

SECTION 10 been added: Accumulation of fine dust may entail the risk of a dust explosion in

the presence of air.

Copyright: Chemiebüro®

www.chemiebuero.de, Phone +49 (0)941-646 353-0, 200628 nbc00056 GB